The Conductance and Thermopower Behavior of Pendent Trans-Coordinated Palladium(II) Complexes in Single-Molecule Junctions

The present work provides insight into the effect of connectivity within isomeric 1,2-bis(2-pyridylethynyl)benzene (bpb) palladium complexes on their electron transmission propertieswithin gold|single-molecule|gold junctions. The ligands 2,2′-((4,5-bis(hexyloxy)-1,2-phenylene)bis-(ethyne-2,1-diyl))b...

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Detalles Bibliográficos
Autores: Bastante Flores, Pablo, Agrait de la Puente, Mario Nicolás, Cea, Pilar, Martin, Santiago, Davidson, Ross J., Al Malki, Wafa, Salthouse, Rebecca J., Batsanov, Andrei S., Lambert, Colin J., Bryce, Martin R.
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/715626
Acceso en línea:http://hdl.handle.net/10486/715626
https://dx.doi.org/10.1021/acsomega.4c06475
Access Level:acceso abierto
Palabra clave:Física
Descripción
Sumario:The present work provides insight into the effect of connectivity within isomeric 1,2-bis(2-pyridylethynyl)benzene (bpb) palladium complexes on their electron transmission propertieswithin gold|single-molecule|gold junctions. The ligands 2,2′-((4,5-bis(hexyloxy)-1,2-phenylene)bis-(ethyne-2,1-diyl))bis(4-(methylthio)pyridine) (Lm) and 6,6′-((4,5-bis(hexyloxy)-1,2-phenylene)bis-(ethyne-2,1-diyl))bis(3-(methylthio)pyridine) (Lp) were synthesized and coordinated with PdCl2 togive the trans-Pd(Lm or p)Cl2 complexes. X-ray photoelectron spectroscopy (XPS) measurementsshed light on the contacting modes of the molecules in the junctions. A combination of scanningtunneling microscopy−break junction (STM−BJ) measurements and density functional theory(DFT) calculations demonstrate that the typical lower conductance of meta- compared with para-connected isomers in a molecular junction was suppressed upon metal coordination. Simultaneouslythere was a modest increase in both conductance and Seebeck coefficient due to the contraction ofthe HOMO−LUMO gap upon metal coordination. It is shown that the low Seebeck coefficient isprimarily a consequence of how the resonances shift relative to the Fermi energy