Sensitive and reversible ammonia gas sensor based on single-walled carbon nanotubes

The present study reports on the fabrication and performance of ammonia sensors based on single-walled carbon nanotubes (SWCNTs) coated with gold nanoparticles (AuNPs). The AuNPs were incorporated onto the SWCNTs using two different methods: sputtering and chemical deposition. The sensors were expos...

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Detalhes bibliográficos
Autores: Machín, Abniel, Cotto, María, Ducongé, José, Morant Zacarés, Carmen, Petrescu, Florian, Márquez, Francisco
Formato: artículo
Fecha de publicación:2023
País:España
Recursos:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/707713
Acesso em linha:http://hdl.handle.net/10486/707713
https://dx.doi.org/10.3390/chemosensors11040247
Access Level:acceso abierto
Palavra-chave:Gas Sensor
Acetone
Sensing
Física
Descrição
Resumo:The present study reports on the fabrication and performance of ammonia sensors based on single-walled carbon nanotubes (SWCNTs) coated with gold nanoparticles (AuNPs). The AuNPs were incorporated onto the SWCNTs using two different methods: sputtering and chemical deposition. The sensors were exposed to controlled concentrations of ammonia at two temperatures, namely, 25 °C and 140 °C, and their response was monitored through successive cycles of ammonia exposure (0.5 ppm and 1.0 ppm) and nitrogen purging. The results demonstrate that the sputtering-based deposition of the AuNPs on SWCNTs led to the best sensor performance, characterized by a rapid increase in resistance values (tresp = 12 s) upon exposure to ammonia and an efficient recovery at 140 °C (trec = 52 s). By contrast, the sensor with chemically impregnated AuNPs exhibited a slower response time (tresp = 25 s) and the same recovery time (trec = 52 s). Additionally, a novel device was developed that combined MoS2-AuNPs (sputtering)-SWCNTs. This sensor was obtained by impregnating nanosheets of MoS2 onto AuNPs (sputtering)-SWCNTs showing improved sensor performance compared to the devices with only AuNPs. In this case, the sensor exhibited a better behavior with a faster recovery of resistance values, even at room temperature. Overall, the study provides valuable insights into the fabrication and optimization of SWCNT-based ammonia sensors for various applications, particularly in detecting and quantifying small amounts of ammonia (concentrations below 1 ppm)