An N-annulated, rylene-based twistacene as scaffold for long supramolecular polymers
The multistep synthesis of the N-annulated rylenecarbodiimide 1 is reported. The large p-surface and the operation of a fourfold array of H-bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying th...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/72554 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/72554 |
| Access Level: | acceso abierto |
| Palabra clave: | AFM cooperativity rylenes supramolecular polymers thermodynamics Química Química orgánica (Química) 23 Química 2306 Química Orgánica |
| Sumario: | The multistep synthesis of the N-annulated rylenecarbodiimide 1 is reported. The large p-surface and the operation of a fourfold array of H-bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying the denaturation model. The operation of these non-covalent interactions affords long 1D-supramolecular polymers that have been visualized by atomic force microscopy (AFM). |
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