Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2

Reaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes [(η5-C5H4)2Si(CH3)2]MCl2 (M = Ti (1) and Zr (2). Along with the predominant product in each case a new titanium and zirconium compound is isolated. Treatment of the complexes 1 and 2 with LiCH2Si(CH3)3 gives...

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Autores: Gómez Ramírez, Rafael|||0000-0001-6448-2414, Cuenca Agreda, José Tomás|||0000-0001-5830-5833, Royo Gracia, Pascual, Herrmann, Wolfgang A., Herdtweck, Eberhardt
Tipo de documento: artigo
Data de publicação:1990
País:España
Recursos:Universidad de Alcalá (UAH)
Repositório:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglês
OAI Identifier:oai:ebuah.uah.es:10017/4636
Acesso em linha:http://hdl.handle.net/10017/4636
https://dx.doi.org/10.1016/0022-328X(90)85219-O
Access Level:Acceso aberto
Palavra-chave:Titanium
Zirconium
Crystal structure
Ciencia
Química inorgánica
Science
Chemistry, inorganic
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repository_id_str
spelling Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2Gómez Ramírez, Rafael|||0000-0001-6448-2414Cuenca Agreda, José Tomás|||0000-0001-5830-5833Royo Gracia, PascualHerrmann, Wolfgang A.Herdtweck, EberhardtTitaniumZirconiumCrystal structureCienciaQuímica inorgánicaScienceChemistry, inorganicReaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes [(η5-C5H4)2Si(CH3)2]MCl2 (M = Ti (1) and Zr (2). Along with the predominant product in each case a new titanium and zirconium compound is isolated. Treatment of the complexes 1 and 2 with LiCH2Si(CH3)3 gives the novel derivatives [(η5-C5H4)2Si(CH3)2]M[CH2Si(CH3)3]2 (M = Ti (4) and Zr (5)) which have been characterized by NMR and mass spectrometry and in the case of 4 by an X-ray structural determination.Deustche Akademische AustauschdienstComisión Interministerial de Ciencia y TenologíaMinisterio de Educación y CienciaElsevier19901990-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4636https://dx.doi.org/10.1016/0022-328X(90)85219-Oreponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengCICYT Not available PB86-0093 Síntesis y aplicaciones de organocomplejos de metales de grupos 4-6Ministerio de Educación y Ciencia Not available MEC-DAAD No. 1%2F51 Bopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/46362026-06-18T11:13:07Z
dc.title.none.fl_str_mv Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
title Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
spellingShingle Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
Gómez Ramírez, Rafael|||0000-0001-6448-2414
Titanium
Zirconium
Crystal structure
Ciencia
Química inorgánica
Science
Chemistry, inorganic
title_short Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
title_full Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
title_fullStr Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
title_full_unstemmed Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
title_sort Stereorigid titanocene and zirconocene derivatives. Synthesis and crystal-structure of the dialkyl complex [η5-η-5-(C5H4)2Si(CH3)2]Ti[CH2Si(CH3)3]2
dc.creator.none.fl_str_mv Gómez Ramírez, Rafael|||0000-0001-6448-2414
Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Royo Gracia, Pascual
Herrmann, Wolfgang A.
Herdtweck, Eberhardt
author Gómez Ramírez, Rafael|||0000-0001-6448-2414
author_facet Gómez Ramírez, Rafael|||0000-0001-6448-2414
Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Royo Gracia, Pascual
Herrmann, Wolfgang A.
Herdtweck, Eberhardt
author_role author
author2 Cuenca Agreda, José Tomás|||0000-0001-5830-5833
Royo Gracia, Pascual
Herrmann, Wolfgang A.
Herdtweck, Eberhardt
author2_role author
author
author
author
dc.subject.none.fl_str_mv Titanium
Zirconium
Crystal structure
Ciencia
Química inorgánica
Science
Chemistry, inorganic
topic Titanium
Zirconium
Crystal structure
Ciencia
Química inorgánica
Science
Chemistry, inorganic
description Reaction of M2′[(η5-C5H4)2Si(CH3)2] (M′ = Li, Na, K) with MCl4 produced the known complexes [(η5-C5H4)2Si(CH3)2]MCl2 (M = Ti (1) and Zr (2). Along with the predominant product in each case a new titanium and zirconium compound is isolated. Treatment of the complexes 1 and 2 with LiCH2Si(CH3)3 gives the novel derivatives [(η5-C5H4)2Si(CH3)2]M[CH2Si(CH3)3]2 (M = Ti (4) and Zr (5)) which have been characterized by NMR and mass spectrometry and in the case of 4 by an X-ray structural determination.
publishDate 1990
dc.date.none.fl_str_mv 1990
1990-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/4636
https://dx.doi.org/10.1016/0022-328X(90)85219-O
url http://hdl.handle.net/10017/4636
https://dx.doi.org/10.1016/0022-328X(90)85219-O
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv CICYT Not available PB86-0093 Síntesis y aplicaciones de organocomplejos de metales de grupos 4-6
Ministerio de Educación y Ciencia Not available MEC-DAAD No. 1%2F51 B
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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