An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance

[EN] An investigation into the intrinsic electrical conductivity of perovskite powders MAPbX(3), where X represents iodine (I), bromine (Br), or chlorine (Cl), was conducted to explore its impact on their photovoltaic performance. Results revealed that MAPbCl(3) demonstrated light absorption ability...

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Autores: Ullah, Shafi, Marí, B.|||0000-0003-0001-419X, Compañ Moreno, Vicente|||0000-0001-8233-7472, Andrio, Andreu, Marí-Guaita, Julia, Ullah, Hanif, Méndez-Blas, Antonio, del Castillo Vázquez, Roxana M.
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/212723
Acceso en línea:https://riunet.upv.es/handle/10251/212723
Access Level:acceso abierto
Palabra clave:Intrinsic electrical conductivity
Perovskite powders
MAPbX(3)
Iodine (I)
Bromine (Br)
Chlorine (Cl)
FISICA APLICADA
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oai_identifier_str oai:riunet.upv.es:10251/212723
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
title An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
spellingShingle An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
Ullah, Shafi
Intrinsic electrical conductivity
Perovskite powders
MAPbX(3)
Iodine (I)
Bromine (Br)
Chlorine (Cl)
FISICA APLICADA
title_short An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
title_full An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
title_fullStr An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
title_full_unstemmed An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
title_sort An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performance
dc.creator.none.fl_str_mv Ullah, Shafi
Marí, B.|||0000-0003-0001-419X
Compañ Moreno, Vicente|||0000-0001-8233-7472
Andrio, Andreu
Marí-Guaita, Julia
Ullah, Hanif
Méndez-Blas, Antonio
del Castillo Vázquez, Roxana M.
author Ullah, Shafi
author_facet Ullah, Shafi
Marí, B.|||0000-0003-0001-419X
Compañ Moreno, Vicente|||0000-0001-8233-7472
Andrio, Andreu
Marí-Guaita, Julia
Ullah, Hanif
Méndez-Blas, Antonio
del Castillo Vázquez, Roxana M.
author_role author
author2 Marí, B.|||0000-0003-0001-419X
Compañ Moreno, Vicente|||0000-0001-8233-7472
Andrio, Andreu
Marí-Guaita, Julia
Ullah, Hanif
Méndez-Blas, Antonio
del Castillo Vázquez, Roxana M.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Física Aplicada
Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial
Instituto de Diseño para la Fabricación y Producción Automatizada
AGENCIA ESTATAL DE INVESTIGACION
UNIVERSIDAD POLITECNICA DE VALENCIA
Benemérita Universidad Autónoma de Puebla
Consejo Nacional de Humanidades, Ciencias y Tecnologías, México
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Intrinsic electrical conductivity
Perovskite powders
MAPbX(3)
Iodine (I)
Bromine (Br)
Chlorine (Cl)
FISICA APLICADA
topic Intrinsic electrical conductivity
Perovskite powders
MAPbX(3)
Iodine (I)
Bromine (Br)
Chlorine (Cl)
FISICA APLICADA
description [EN] An investigation into the intrinsic electrical conductivity of perovskite powders MAPbX(3), where X represents iodine (I), bromine (Br), or chlorine (Cl), was conducted to explore its impact on their photovoltaic performance. Results revealed that MAPbCl(3) demonstrated light absorption ability in the ultraviolet and visible regions, while MAPbBr(3) showed capacity for light absorption at longer wavelengths in the visible spectrum. On the other hand, MAPbI(3) exhibited good absorption at longer wavelengths, indicating its ability to absorb light in the near-infrared region. The optical bandgap of each perovskite was determined to be 2.90 eV for MAPbCl(3), 2.20 eV for MAPbBr(3), and 1.47 eV for MAPbI(3). The electrical conductivities of these powders were measured in-plane using the four-probe method and through-plane by electrochemical impedance spectroscopy (EIS). Electrochemical impedance spectroscopy (EIS) studies revealed a significant change in the conductivity of the MAPbI(3) perovskite at temperatures between 80 degrees C and 100 degrees C. This change could be attributed to structural modifications induced when the temperature exceeds these values. The through-plane conductivity changed from 3 x 10(-8) S cm(-1) at 60 degrees C to approximately 6 x 10(-5) S cm(-1) at 120 degrees C and around 2 x 10(-3) S cm(-1) at 200 degrees C. Meanwhile, the sheet conductivity (in-plane conductivity) measurements performed at ambient temperature reveal that sheet conductivities are 489 x 10(3) S m(-1), 486 x 10(3) S m(-1) and 510 x 10(3) S m(-1) for MAPbBr(3), MAPbCl(3) and MAPbI(3), respectively. This study provides valuable insights for optimizing the performance of perovskite solar cells. Understanding how dopants influence the electrical conductivity and photovoltaic properties of the perovskite material, this work will enable researchers to design and engineer more efficient and stable solar cell devices based on MAPbX(3) perovskites.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-02-22
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/212723
url https://riunet.upv.es/handle/10251/212723
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2019-107137RB-C21 MEJORANDO LA PRODUCCION DE ENERGIA SOLAR CON PEROVSKITAS INORGANICAS.SINTESIS
Universitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-10-20 SINTESIS Y CARACTERIZACIÓN DE SEMICONDUCTORES V: SnS2 CON BANDA INTERMEDIA PARA APLICACIONES FOTOCATALITICS Y FOTOVOLTAICAS AVANZADAS
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv The Royal Society of Chemistry
publisher.none.fl_str_mv The Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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spelling An intrinsic electrical conductivity study of perovskite powders MAPbX3 (X = I, Br, Cl) to investigate its effect on their photovoltaic performanceUllah, ShafiMarí, B.|||0000-0003-0001-419XCompañ Moreno, Vicente|||0000-0001-8233-7472Andrio, AndreuMarí-Guaita, JuliaUllah, HanifMéndez-Blas, Antoniodel Castillo Vázquez, Roxana M.Intrinsic electrical conductivityPerovskite powdersMAPbX(3)Iodine (I)Bromine (Br)Chlorine (Cl)FISICA APLICADA[EN] An investigation into the intrinsic electrical conductivity of perovskite powders MAPbX(3), where X represents iodine (I), bromine (Br), or chlorine (Cl), was conducted to explore its impact on their photovoltaic performance. Results revealed that MAPbCl(3) demonstrated light absorption ability in the ultraviolet and visible regions, while MAPbBr(3) showed capacity for light absorption at longer wavelengths in the visible spectrum. On the other hand, MAPbI(3) exhibited good absorption at longer wavelengths, indicating its ability to absorb light in the near-infrared region. The optical bandgap of each perovskite was determined to be 2.90 eV for MAPbCl(3), 2.20 eV for MAPbBr(3), and 1.47 eV for MAPbI(3). The electrical conductivities of these powders were measured in-plane using the four-probe method and through-plane by electrochemical impedance spectroscopy (EIS). Electrochemical impedance spectroscopy (EIS) studies revealed a significant change in the conductivity of the MAPbI(3) perovskite at temperatures between 80 degrees C and 100 degrees C. This change could be attributed to structural modifications induced when the temperature exceeds these values. The through-plane conductivity changed from 3 x 10(-8) S cm(-1) at 60 degrees C to approximately 6 x 10(-5) S cm(-1) at 120 degrees C and around 2 x 10(-3) S cm(-1) at 200 degrees C. Meanwhile, the sheet conductivity (in-plane conductivity) measurements performed at ambient temperature reveal that sheet conductivities are 489 x 10(3) S m(-1), 486 x 10(3) S m(-1) and 510 x 10(3) S m(-1) for MAPbBr(3), MAPbCl(3) and MAPbI(3), respectively. This study provides valuable insights for optimizing the performance of perovskite solar cells. Understanding how dopants influence the electrical conductivity and photovoltaic properties of the perovskite material, this work will enable researchers to design and engineer more efficient and stable solar cell devices based on MAPbX(3) perovskites.The author Shafi Ullah acknowledges the post-doctoral contract supported by the RRHH (Human Resources for Research) program, postdoctoral contract (PAID-10-20) Universitat Politecnica de Valencia (UPV), and Ministerio de Economia y Competitividad under Grant Number PID 2019-107137 RB-C21. Antonio Mendez-Blas acknowledges CONACYT, Mexico (Sabbatical Grant 2022) and VIEP-BUAP.The Royal Society of ChemistryDepartamento de Física AplicadaEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialInstituto de Diseño para la Fabricación y Producción AutomatizadaAGENCIA ESTATAL DE INVESTIGACIONUNIVERSIDAD POLITECNICA DE VALENCIABenemérita Universidad Autónoma de PueblaConsejo Nacional de Humanidades, Ciencias y Tecnologías, MéxicoRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-02-22journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/212723reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2019-107137RB-C21 MEJORANDO LA PRODUCCION DE ENERGIA SOLAR CON PEROVSKITAS INORGANICAS.SINTESISUniversitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-10-20 SINTESIS Y CARACTERIZACIÓN DE SEMICONDUCTORES V: SnS2 CON BANDA INTERMEDIA PARA APLICACIONES FOTOCATALITICS Y FOTOVOLTAICAS AVANZADASopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2127232026-06-13T07:49:27Z
score 15,81155

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