A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters

Mesoporous silica functionalized with octadecyl groups (denoted as SBA-15-C18) was prepared and characterized. The adsorption capacity of the prepared SBA-15-C18 for a mixture of twelve endocrine disrupting compounds (synthetic and natural estrogenic hormones) in aqueous media was evaluated by off-l...

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Detalles Bibliográficos
Autores: Gañán, Judith, Morante-Zarcero, Sonia, Pérez-Quintanilla, Damián, Sierra, Isabel
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/13120
Acceso en línea:http://hdl.handle.net/10115/13120
Access Level:acceso embargado
Palabra clave:Materiales
Química
Solid-phase extraction
Mesoporous silica
estrogens
Water
Endocrine disrupting compounds
23 Química
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oai_identifier_str oai:burjcdigital.urjc.es:10115/13120
network_acronym_str ES
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repository_id_str
spelling A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from watersGañán, JudithMorante-Zarcero, SoniaPérez-Quintanilla, DamiánSierra, IsabelMaterialesQuímicaSolid-phase extractionMesoporous silicaestrogensWaterEndocrine disrupting compounds23 QuímicaMesoporous silica functionalized with octadecyl groups (denoted as SBA-15-C18) was prepared and characterized. The adsorption capacity of the prepared SBA-15-C18 for a mixture of twelve endocrine disrupting compounds (synthetic and natural estrogenic hormones) in aqueous media was evaluated by off-line solid-phase extraction (SPE) and compared with a commercial phase for SPE (ExtraBondR C18). Analytes were determined by high performance liquid chromatography with UV-Vis detection. Under optimized conditions (100 mg of SBA-15-C18 sorbent; conditioning: 2 mL methanol and 2 mL Milli-Q water; loading: 150 mL water sample; washing: 5 mL Milli-Q water; elution: 2 mL methanol; flow rate 0.5 mL min-1) the preconcentration factor achieved was 103. The analytical characteristics of this methodology were evaluated, showing good precision, accuracy and linerarity, with method quantification limits (MQL) between 0.16 and 3-00 ¿g L-1. The SBA-15-C18 material enabled the extraction of the twelve estrogenic hormones in tap water (pH 6.6), mineral water (pH 5.0), ground water (pH 7.3), river water (pH 5.0) and effluent wastewater (pH 5.0) with recoveries between 71 and 112% at the lower level studied (MQL).Royal Society of Chemistry201520152015info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10115/13120reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésS2013/ABI-3028Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/embargoedAccessoai:burjcdigital.urjc.es:10115/131202026-06-24T12:48:17Z
dc.title.none.fl_str_mv A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
title A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
spellingShingle A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
Gañán, Judith
Materiales
Química
Solid-phase extraction
Mesoporous silica
estrogens
Water
Endocrine disrupting compounds
23 Química
title_short A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
title_full A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
title_fullStr A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
title_full_unstemmed A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
title_sort A novel hybrid mesostructured silica for the solid-phase extraction of estrogenic hormones from waters
dc.creator.none.fl_str_mv Gañán, Judith
Morante-Zarcero, Sonia
Pérez-Quintanilla, Damián
Sierra, Isabel
author Gañán, Judith
author_facet Gañán, Judith
Morante-Zarcero, Sonia
Pérez-Quintanilla, Damián
Sierra, Isabel
author_role author
author2 Morante-Zarcero, Sonia
Pérez-Quintanilla, Damián
Sierra, Isabel
author2_role author
author
author
dc.subject.none.fl_str_mv Materiales
Química
Solid-phase extraction
Mesoporous silica
estrogens
Water
Endocrine disrupting compounds
23 Química
topic Materiales
Química
Solid-phase extraction
Mesoporous silica
estrogens
Water
Endocrine disrupting compounds
23 Química
description Mesoporous silica functionalized with octadecyl groups (denoted as SBA-15-C18) was prepared and characterized. The adsorption capacity of the prepared SBA-15-C18 for a mixture of twelve endocrine disrupting compounds (synthetic and natural estrogenic hormones) in aqueous media was evaluated by off-line solid-phase extraction (SPE) and compared with a commercial phase for SPE (ExtraBondR C18). Analytes were determined by high performance liquid chromatography with UV-Vis detection. Under optimized conditions (100 mg of SBA-15-C18 sorbent; conditioning: 2 mL methanol and 2 mL Milli-Q water; loading: 150 mL water sample; washing: 5 mL Milli-Q water; elution: 2 mL methanol; flow rate 0.5 mL min-1) the preconcentration factor achieved was 103. The analytical characteristics of this methodology were evaluated, showing good precision, accuracy and linerarity, with method quantification limits (MQL) between 0.16 and 3-00 ¿g L-1. The SBA-15-C18 material enabled the extraction of the twelve estrogenic hormones in tap water (pH 6.6), mineral water (pH 5.0), ground water (pH 7.3), river water (pH 5.0) and effluent wastewater (pH 5.0) with recoveries between 71 and 112% at the lower level studied (MQL).
publishDate 2015
dc.date.none.fl_str_mv 2015
2015
2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10115/13120
url http://hdl.handle.net/10115/13120
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv S2013/ABI-3028
dc.rights.none.fl_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
info:eu-repo/semantics/embargoedAccess
rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv embargoedAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
instname:Universidad Rey Juan Carlos
instname_str Universidad Rey Juan Carlos
reponame_str BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
collection BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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