Palladium-Catalyzed Tandem Cycloisomerization/Cross-Coupling of Carbonyl- and Imine-Tethered Alkylidenecyclopropanes

A palladium catalytic system is reported for the divergent tandem cycloisomerization and cross-coupling of carbonyl- and imine-tethered alkylidenecyclopropanes (ACPs). The selection of ancillary ligands is pivotal for the interception of the heteropalladacyclic intermediates with different external...

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Detalles Bibliográficos
Autores: Verdugo Leal, Felipe Ignacio, Rodiño Balboa, Ricardo, Calvelo Souto, Martín, Mascareñas Cid, José Luis, López García, Fernando José
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/28826
Acceso en línea:http://hdl.handle.net/10347/28826
Access Level:acceso abierto
Descripción
Sumario:A palladium catalytic system is reported for the divergent tandem cycloisomerization and cross-coupling of carbonyl- and imine-tethered alkylidenecyclopropanes (ACPs). The selection of ancillary ligands is pivotal for the interception of the heteropalladacyclic intermediates with different external nucleophiles

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