Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite

Pharmaceutical residues in water and wastewater have become a worldwide problem with environmental and public health consequences. Antibiotics are of special importance because of the emergence of antibiotic-resistant genes. This study evaluates the adsorptive removal of four common fluoroquinolone...

Descripción completa

Detalles Bibliográficos
Autores: Haciosmanoglu, Gul Gulenay, Arenas Molina, Marina, Mejías Padilla, Carmen, Martín Bueno, Julia, Santos Morcillo, Juan Luis, Aparicio Gómez, Irene, Alonso Álvarez, Esteban
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/156755
Acceso en línea:https://hdl.handle.net/11441/156755
https://doi.org/10.3390/ijerph20032646
Access Level:acceso abierto
Palabra clave:Adsorption
Colemanite
Fluoroquinolone antibiotics
Wastewater
Water
id ES_9bb792dce236af436d56b4ad2b8dbce7
oai_identifier_str oai:idus.us.es:11441/156755
network_acronym_str ES
network_name_str España
repository_id_str
spelling Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by ColemaniteHaciosmanoglu, Gul GulenayArenas Molina, MarinaMejías Padilla, CarmenMartín Bueno, JuliaSantos Morcillo, Juan LuisAparicio Gómez, IreneAlonso Álvarez, EstebanAdsorptionColemaniteFluoroquinolone antibioticsWastewaterWaterPharmaceutical residues in water and wastewater have become a worldwide problem with environmental and public health consequences. Antibiotics are of special importance because of the emergence of antibiotic-resistant genes. This study evaluates the adsorptive removal of four common fluoroquinolone antibiotics by using natural colemanite as an alternative adsorbent for the first time. Batch adsorption experiments were conducted for the mixture of fluoroquinolones as well as for individual compounds during the isotherm studies. Adsorption kinetic results indicated that the process followed the pseudo-second-order (PSO) model, while the Langmuir model described the sorption isotherms. The effects of pH and temperature on adsorption performance were determined, and the results indicated that the adsorption was endothermic and spontaneous, with increasing randomness at the solid–liquid interface. The effects of real water and wastewater matrices were tested by using tap water, surface water, and wastewater samples. Reusability experiments based on five adsorption–desorption cycles indicated that the adsorption performance was mostly retained after five cycles. The adsorption mechanism was elucidated based the material characterization before and after adsorption. The results indicate that colemanite can be used as an effective and reusable adsorbent for fluoroquinolone antibiotics as well as for other pollutants with similar physicochemical properties.Ministerio de Ciencia e Innovación PID2020-117641RB-I00Scientific and Technological Research Council of Turkey 1059B191900163Multidisciplinary Digital Publishing Institute (MDPI)Química AnalíticaMinisterio de Ciencia e Innovación (MICIN). EspañaScientific and Technological Research Council of Turkey2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/156755https://doi.org/10.3390/ijerph20032646reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésInternational Journal of Environmental Research and Public Health, 20 (3), 2646.PID2020-117641RB-I001059B191900163https://doi.org/10.3390/ijerph20032646info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1567552026-06-17T12:51:07Z
dc.title.none.fl_str_mv Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
title Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
spellingShingle Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
Haciosmanoglu, Gul Gulenay
Adsorption
Colemanite
Fluoroquinolone antibiotics
Wastewater
Water
title_short Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
title_full Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
title_fullStr Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
title_full_unstemmed Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
title_sort Adsorption of Fluoroquinolone Antibiotics from Water and Wastewater by Colemanite
dc.creator.none.fl_str_mv Haciosmanoglu, Gul Gulenay
Arenas Molina, Marina
Mejías Padilla, Carmen
Martín Bueno, Julia
Santos Morcillo, Juan Luis
Aparicio Gómez, Irene
Alonso Álvarez, Esteban
author Haciosmanoglu, Gul Gulenay
author_facet Haciosmanoglu, Gul Gulenay
Arenas Molina, Marina
Mejías Padilla, Carmen
Martín Bueno, Julia
Santos Morcillo, Juan Luis
Aparicio Gómez, Irene
Alonso Álvarez, Esteban
author_role author
author2 Arenas Molina, Marina
Mejías Padilla, Carmen
Martín Bueno, Julia
Santos Morcillo, Juan Luis
Aparicio Gómez, Irene
Alonso Álvarez, Esteban
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Química Analítica
Ministerio de Ciencia e Innovación (MICIN). España
Scientific and Technological Research Council of Turkey
dc.subject.none.fl_str_mv Adsorption
Colemanite
Fluoroquinolone antibiotics
Wastewater
Water
topic Adsorption
Colemanite
Fluoroquinolone antibiotics
Wastewater
Water
description Pharmaceutical residues in water and wastewater have become a worldwide problem with environmental and public health consequences. Antibiotics are of special importance because of the emergence of antibiotic-resistant genes. This study evaluates the adsorptive removal of four common fluoroquinolone antibiotics by using natural colemanite as an alternative adsorbent for the first time. Batch adsorption experiments were conducted for the mixture of fluoroquinolones as well as for individual compounds during the isotherm studies. Adsorption kinetic results indicated that the process followed the pseudo-second-order (PSO) model, while the Langmuir model described the sorption isotherms. The effects of pH and temperature on adsorption performance were determined, and the results indicated that the adsorption was endothermic and spontaneous, with increasing randomness at the solid–liquid interface. The effects of real water and wastewater matrices were tested by using tap water, surface water, and wastewater samples. Reusability experiments based on five adsorption–desorption cycles indicated that the adsorption performance was mostly retained after five cycles. The adsorption mechanism was elucidated based the material characterization before and after adsorption. The results indicate that colemanite can be used as an effective and reusable adsorbent for fluoroquinolone antibiotics as well as for other pollutants with similar physicochemical properties.
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/156755
https://doi.org/10.3390/ijerph20032646
url https://hdl.handle.net/11441/156755
https://doi.org/10.3390/ijerph20032646
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv International Journal of Environmental Research and Public Health, 20 (3), 2646.
PID2020-117641RB-I00
1059B191900163
https://doi.org/10.3390/ijerph20032646
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute (MDPI)
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869414578035621888
score 15,812429

Similares en LA Referencia