Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)]
Reactions of the η5-cyclopentadienyl-η1-amido dimethyl titanium derivative [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}Me2] (1) with tris(pentafluorophenyl)borane B(C6F5)3 in hexane at room temperature yield a thermally stable bright yellow microcrystaline solid identified by elemental analysis as [Ti{η5-C5H4Si...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 1999 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4232 |
| Acceso en línea: | http://hdl.handle.net/10017/4232 https://dx.doi.org/10.1016/S0022-328X(99)00340-X |
| Access Level: | acceso abierto |
| Palabra clave: | Amido-silylcyclopentadienyl Cationic alkyltitanium complexes Titanium Ciencia Química inorgánica Science Chemistry, inorganic |
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oai:ebuah.uah.es:10017/4232 |
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Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)]Gómez Ramírez, Rafael|||0000-0001-6448-2414Gómez Sal, Pilar|||0000-0002-9279-210XReal Manzano, Pedro Ángel delRoyo Gracia, PascualAmido-silylcyclopentadienylCationic alkyltitanium complexesTitaniumCienciaQuímica inorgánicaScienceChemistry, inorganicReactions of the η5-cyclopentadienyl-η1-amido dimethyl titanium derivative [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}Me2] (1) with tris(pentafluorophenyl)borane B(C6F5)3 in hexane at room temperature yield a thermally stable bright yellow microcrystaline solid identified by elemental analysis as [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}Me{MeB(C6F5)3}] (2). A solution of 1 in CD2Cl2 at −78°C affords the ion-pair complex 2, while in C6D6 it is slowly converted into the new neutral complex [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}{CH2B(C6F5)2}(C6F5)] (3). Complex 3 is the unique product obtained after stirring compound 2 or a mixture of complex 1 and B(C6F5)3 in toluene or benzene for 12 h at room temperature. The molecular structure of complex 3 has been determined by diffraction methods.Ministerio de Ciencia y TecnologíaElsevier19991999-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4232https://dx.doi.org/10.1016/S0022-328X(99)00340-Xreponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengMICYT Not available PB97-0776 Complejos ciclopentadienilo de metales de los primeros grupos de transición y sus aplicaciones en procesos estequiométricos y catalíticosopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/42322026-06-18T11:13:07Z |
| dc.title.none.fl_str_mv |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| title |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| spellingShingle |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] Gómez Ramírez, Rafael|||0000-0001-6448-2414 Amido-silylcyclopentadienyl Cationic alkyltitanium complexes Titanium Ciencia Química inorgánica Science Chemistry, inorganic |
| title_short |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| title_full |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| title_fullStr |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| title_full_unstemmed |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| title_sort |
Cationic species derived from the η1-amidosilyl-η5-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{η5-C5H4SiMe2[η1-N(2,6-Me2C6H3)]}{CH2B(C6F5)2}(C6F5)] |
| dc.creator.none.fl_str_mv |
Gómez Ramírez, Rafael|||0000-0001-6448-2414 Gómez Sal, Pilar|||0000-0002-9279-210X Real Manzano, Pedro Ángel del Royo Gracia, Pascual |
| author |
Gómez Ramírez, Rafael|||0000-0001-6448-2414 |
| author_facet |
Gómez Ramírez, Rafael|||0000-0001-6448-2414 Gómez Sal, Pilar|||0000-0002-9279-210X Real Manzano, Pedro Ángel del Royo Gracia, Pascual |
| author_role |
author |
| author2 |
Gómez Sal, Pilar|||0000-0002-9279-210X Real Manzano, Pedro Ángel del Royo Gracia, Pascual |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Amido-silylcyclopentadienyl Cationic alkyltitanium complexes Titanium Ciencia Química inorgánica Science Chemistry, inorganic |
| topic |
Amido-silylcyclopentadienyl Cationic alkyltitanium complexes Titanium Ciencia Química inorgánica Science Chemistry, inorganic |
| description |
Reactions of the η5-cyclopentadienyl-η1-amido dimethyl titanium derivative [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}Me2] (1) with tris(pentafluorophenyl)borane B(C6F5)3 in hexane at room temperature yield a thermally stable bright yellow microcrystaline solid identified by elemental analysis as [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}Me{MeB(C6F5)3}] (2). A solution of 1 in CD2Cl2 at −78°C affords the ion-pair complex 2, while in C6D6 it is slowly converted into the new neutral complex [Ti{η5-C5H4SiMe2[η1-N(C6H3Me2)]}{CH2B(C6F5)2}(C6F5)] (3). Complex 3 is the unique product obtained after stirring compound 2 or a mixture of complex 1 and B(C6F5)3 in toluene or benzene for 12 h at room temperature. The molecular structure of complex 3 has been determined by diffraction methods. |
| publishDate |
1999 |
| dc.date.none.fl_str_mv |
1999 1999-01-01 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 NA http://purl.org/coar/version/c_be7fb7dd8ff6fe43 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10017/4232 https://dx.doi.org/10.1016/S0022-328X(99)00340-X |
| url |
http://hdl.handle.net/10017/4232 https://dx.doi.org/10.1016/S0022-328X(99)00340-X |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.relation.none.fl_str_mv |
MICYT Not available PB97-0776 Complejos ciclopentadienilo de metales de los primeros grupos de transición y sus aplicaciones en procesos estequiométricos y catalíticos |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:e_Buah Biblioteca Digital Universidad de Alcalá instname:Universidad de Alcalá (UAH) |
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Universidad de Alcalá (UAH) |
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e_Buah Biblioteca Digital Universidad de Alcalá |
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e_Buah Biblioteca Digital Universidad de Alcalá |
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15.300719 |