Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites
Eutectogels are an emerging family of soft ionic materials alternative to ionic liquid gels and organogels, offering fresh perspectives for designing functional dynamic platforms in water-free environments. Herein, the first example of mixed ionic and electronic conducting supramolecular eutectogel...
| Autores: | , , , , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/415285 |
| Acceso en línea: | http://hdl.handle.net/10261/415285 https://api.elsevier.com/content/abstract/scopus_id/85159206969 |
| Access Level: | acceso abierto |
| Palabra clave: | Bioimaging Deep Eutectic Solvents Ionic Liquids Organic Mixed Ionic-Electronic Conductors Supramolecular Eutectogels |
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Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel CompositesCriado-González, MiryamAlegret, NuriaFracaroli, Alejandro M.Mantione, DanieleGuzmán-González, GregorioDel Olmo, RafaelTashiro, KentaroTomé, Liliana C.Picchio, Matias L.Mecerreyes, DavidBioimagingDeep Eutectic SolventsIonic LiquidsOrganic Mixed Ionic-Electronic ConductorsSupramolecular EutectogelsEutectogels are an emerging family of soft ionic materials alternative to ionic liquid gels and organogels, offering fresh perspectives for designing functional dynamic platforms in water-free environments. Herein, the first example of mixed ionic and electronic conducting supramolecular eutectogel composites is reported. A fluorescent glutamic acid-derived low-molecular-weight gelator (LMWG) was found to self-assemble into nanofibrillar networks in deep eutectic solvents (DES)/poly(3,4-ethylenedioxythiophene) (PEDOT): chondroitin sulfate dispersions. These dynamic materials displayed excellent injectability and self-healing properties, high ionic conductivity (up to 10-2 S cm-1 ), good biocompatibility, and fluorescence imaging ability. This set of features turns the mixed conducting supramolecular eutectogels into promising adaptive materials for bioimaging and electrostimulation applications.This work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under the grant agreement No 823989 “IONBIKE”. The financial support received from CONICET and ANPCyT (Argenti-na) is also gratefully acknowledged. M. C.-G. thanks Emakiker Grant Program of POLYMAT. L. C. T. is gratefu lto Fundação para a Ciência e a Tecnologia (FCT/MCTES) in Portugal for her research contract under ScientificEmployment Stimulus (2020.01555.CEECIND), and Asso-ciate Laboratory for Green Chemistry—LAQV, which isalso financed by FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020). D. M. thanks “Ayuda RYC2021-031668-I financiada por MCIN/AEI/10.13039/501100011033 y por laUnión Europea Next GenerationEU/PRTR”. The authors thank the technical and human support provided by SGIker(UPV/EHU/ERDF, EU).Peer reviewedWiley-VCHEuropean CommissionConsejo Nacional de Investigaciones Científicas y Técnicas (Argentina)Agencia Nacional de Promoción Científica y Tecnológica (Argentina)Fundação para a Ciência e a Tecnologia (Portugal)Ministerio de Ciencia e Innovación (España)Criado-González, Miryam [0000-0002-5502-892X]202620262023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/415285https://api.elsevier.com/content/abstract/scopus_id/85159206969reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/HE/823989info:eu-repo/grantAgreement///RYC2021-031668-Ihttps://doi.org/10.1002/anie.202301489Noinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/4152852026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| title |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| spellingShingle |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites Criado-González, Miryam Bioimaging Deep Eutectic Solvents Ionic Liquids Organic Mixed Ionic-Electronic Conductors Supramolecular Eutectogels |
| title_short |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| title_full |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| title_fullStr |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| title_full_unstemmed |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| title_sort |
Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites |
| dc.creator.none.fl_str_mv |
Criado-González, Miryam Alegret, Nuria Fracaroli, Alejandro M. Mantione, Daniele Guzmán-González, Gregorio Del Olmo, Rafael Tashiro, Kentaro Tomé, Liliana C. Picchio, Matias L. Mecerreyes, David |
| author |
Criado-González, Miryam |
| author_facet |
Criado-González, Miryam Alegret, Nuria Fracaroli, Alejandro M. Mantione, Daniele Guzmán-González, Gregorio Del Olmo, Rafael Tashiro, Kentaro Tomé, Liliana C. Picchio, Matias L. Mecerreyes, David |
| author_role |
author |
| author2 |
Alegret, Nuria Fracaroli, Alejandro M. Mantione, Daniele Guzmán-González, Gregorio Del Olmo, Rafael Tashiro, Kentaro Tomé, Liliana C. Picchio, Matias L. Mecerreyes, David |
| author2_role |
author author author author author author author author author |
| dc.contributor.none.fl_str_mv |
European Commission Consejo Nacional de Investigaciones Científicas y Técnicas (Argentina) Agencia Nacional de Promoción Científica y Tecnológica (Argentina) Fundação para a Ciência e a Tecnologia (Portugal) Ministerio de Ciencia e Innovación (España) Criado-González, Miryam [0000-0002-5502-892X] |
| dc.subject.none.fl_str_mv |
Bioimaging Deep Eutectic Solvents Ionic Liquids Organic Mixed Ionic-Electronic Conductors Supramolecular Eutectogels |
| topic |
Bioimaging Deep Eutectic Solvents Ionic Liquids Organic Mixed Ionic-Electronic Conductors Supramolecular Eutectogels |
| description |
Eutectogels are an emerging family of soft ionic materials alternative to ionic liquid gels and organogels, offering fresh perspectives for designing functional dynamic platforms in water-free environments. Herein, the first example of mixed ionic and electronic conducting supramolecular eutectogel composites is reported. A fluorescent glutamic acid-derived low-molecular-weight gelator (LMWG) was found to self-assemble into nanofibrillar networks in deep eutectic solvents (DES)/poly(3,4-ethylenedioxythiophene) (PEDOT): chondroitin sulfate dispersions. These dynamic materials displayed excellent injectability and self-healing properties, high ionic conductivity (up to 10-2 S cm-1 ), good biocompatibility, and fluorescence imaging ability. This set of features turns the mixed conducting supramolecular eutectogels into promising adaptive materials for bioimaging and electrostimulation applications. |
| publishDate |
2023 |
| dc.date.none.fl_str_mv |
2023 2026 2026 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/415285 https://api.elsevier.com/content/abstract/scopus_id/85159206969 |
| url |
http://hdl.handle.net/10261/415285 https://api.elsevier.com/content/abstract/scopus_id/85159206969 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/HE/823989 info:eu-repo/grantAgreement///RYC2021-031668-I https://doi.org/10.1002/anie.202301489 No |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Wiley-VCH |
| publisher.none.fl_str_mv |
Wiley-VCH |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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15,81155 |