Dodecanuclear [NiII8Ln4] clusters: rings of corner-sharing {NiII2Ln2} cubanes (Ln = Dy, Gd, Y}
[Description of methods used for collection/generation of data] Magnetisation data were collected on MPMS-XL and MPMS3 SQUID magnetometers equipped with 5 and 7 T magnets, respectively. Diamagnetic corrections were applied using Pascal's constants. Heat capacity measurements were carried out on...
| Autores: | , , , , , , , , |
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| Tipo de recurso: | conjunto de datos |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/380383 |
| Acceso en línea: | http://hdl.handle.net/10261/380383 https://doi.org/10.20350/digitalCSIC/17066 |
| Access Level: | acceso abierto |
| Palabra clave: | Inorganic Chemistry Lanthanides Magnetism Magnetocaloric effect |
| Sumario: | [Description of methods used for collection/generation of data] Magnetisation data were collected on MPMS-XL and MPMS3 SQUID magnetometers equipped with 5 and 7 T magnets, respectively. Diamagnetic corrections were applied using Pascal's constants. Heat capacity measurements were carried out on a PPMS equipped with a 9 T magnet and a 3He cryostat, using a thin pressed pellet (ca. 1 mg) of a polycrystalline sample of 2, thermalized by ca. 0.2 mg of Apiezon N grease, whose contribution was subtracted using a phenomenological expression. |
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