(C5Me5)SiMe3 as a mild and effective reagent for transfer of the C5Me5 ring: an improved route to monopentamethylcyclopentadienyl trihalides of the group-4 elements
The reaction between (C5Me5)SiMe3 and group 4 element tetrahalides MX4 (M=Ti, X=Cl, Br, I; M=Zr and Hf, X=Cl) gives the corresponding (η5-C5Me5)MX3 derivatives in nearly quantitative yields in a one-step procedure without the need for further purification.
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 1988 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4653 |
| Acceso en línea: | http://hdl.handle.net/10017/4653 https://dx.doi.org/10.1016/0022-328X(88)80551-5 |
| Access Level: | acceso abierto |
| Palabra clave: | Monopentamethylcyclopentadienyl trihalides Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | The reaction between (C5Me5)SiMe3 and group 4 element tetrahalides MX4 (M=Ti, X=Cl, Br, I; M=Zr and Hf, X=Cl) gives the corresponding (η5-C5Me5)MX3 derivatives in nearly quantitative yields in a one-step procedure without the need for further purification. |
|---|