Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins

Artículo CrystEngComm 2013

Bibliographic Details
Authors: Fidalgo Marijuán, Arkaitz, Barandika Argoitia, Miren Gotzone, Bazán Blau, Begoña del Pilar, Urtiaga Greaves, Miren Karmele, Arriortua Marcaida, María Isabel
Format: article
Publication Date:2013
Country:España
Institution:Universidad del País Vasco
Repository:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/17644
Online Access:http://hdl.handle.net/10810/17644
Access Level:Open access
Keyword:metalloporphyrin
MOF
crystallochemical analysis
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spelling Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrinsFidalgo Marijuán, ArkaitzBarandika Argoitia, Miren GotzoneBazán Blau, Begoña del PilarUrtiaga Greaves, Miren KarmeleArriortua Marcaida, María IsabelmetalloporphyrinMOFcrystallochemical analysisArtículo CrystEngComm 2013Two new CoP–bipy compounds have been synthesised and characterised, where P is TPP for compound 1 (TPP = meso-tetraphenylporphyrin) and TPPS for compound 2 (TPPS = meso-tetraphenylporphinetetrasulfonic acid tetrasodium salt), and bipy is 4,49-bipyridine. Compound 1 consists of 1D polymers packed in a network where isolated porphyrin units are immobilized by an extended p-bond system. On the other hand, as we are aware, compound 2 is the first Co–TPPS compound in literature. It also consists of 1D polymers that are formed by the alternation of two distinct metal centres. These unprecedented polymers are packed forming cavities where crystallization molecules of water are located. The robustness of the hydrogen bond system and a topology based on nterpenetrated nets are responsible for the high thermal stability of compound 2. Additionally, a crystallochemical study confirmed the existence of a correlation between the degree of ruffled distortion of the porphyrin macrocycle and some selected dihedral angles and distances for CoII porphyrins in literature.Ministerio de Ciencia e Innovacion: (MAT2010-15375), Gobierno Vasco: (Basque University System Research Groups, IT-630-13)RSC Publishing201620162013info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/17644reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoIngléshttp://pubs.rsc.org/en/content/articlelanding/2013/ce/c3ce40161h#!divAbstractinfo:eu-repo/semantics/openAccess© The Royal Society of Chemistry 2013oai:addi.ehu.eus:10810/176442026-06-18T09:23:17Z
dc.title.none.fl_str_mv Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
title Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
spellingShingle Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
Fidalgo Marijuán, Arkaitz
metalloporphyrin
MOF
crystallochemical analysis
title_short Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
title_full Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
title_fullStr Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
title_full_unstemmed Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
title_sort Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
dc.creator.none.fl_str_mv Fidalgo Marijuán, Arkaitz
Barandika Argoitia, Miren Gotzone
Bazán Blau, Begoña del Pilar
Urtiaga Greaves, Miren Karmele
Arriortua Marcaida, María Isabel
author Fidalgo Marijuán, Arkaitz
author_facet Fidalgo Marijuán, Arkaitz
Barandika Argoitia, Miren Gotzone
Bazán Blau, Begoña del Pilar
Urtiaga Greaves, Miren Karmele
Arriortua Marcaida, María Isabel
author_role author
author2 Barandika Argoitia, Miren Gotzone
Bazán Blau, Begoña del Pilar
Urtiaga Greaves, Miren Karmele
Arriortua Marcaida, María Isabel
author2_role author
author
author
author
dc.subject.none.fl_str_mv metalloporphyrin
MOF
crystallochemical analysis
topic metalloporphyrin
MOF
crystallochemical analysis
description Artículo CrystEngComm 2013
publishDate 2013
dc.date.none.fl_str_mv 2013
2016
2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/17644
url http://hdl.handle.net/10810/17644
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://pubs.rsc.org/en/content/articlelanding/2013/ce/c3ce40161h#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
© The Royal Society of Chemistry 2013
eu_rights_str_mv openAccess
rights_invalid_str_mv © The Royal Society of Chemistry 2013
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv RSC Publishing
publisher.none.fl_str_mv RSC Publishing
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869414077638377472
score 15,198674

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