Editorial: pyrophosphates and polyphosphates in plants and microorganisms

Phosphorus is the fifth most abundant chemical element in living cells. Microorganisms and plants take up phosphorus as dissolved (ortho)phosphate (Pi), that is often limited due to the formation of sparingly soluble complexes in soil; on the other hand, overapplication of phosphate fertilizer gener...

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Detalhes bibliográficos
Autores: Pérez Castiñeira, José Román, Docampo, Roberto, Ezawa, Tatsuhiro, Serrano, Aurelio
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Recursos:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/130578
Acesso em linha:https://hdl.handle.net/11441/130578
https://doi.org/10.3389/fpls.2021.653416
Access Level:acceso abierto
Palavra-chave:Pyrophosphate
Polyphosphates
Phosphate metabolism
PPI
PolyP
Descrição
Resumo:Phosphorus is the fifth most abundant chemical element in living cells. Microorganisms and plants take up phosphorus as dissolved (ortho)phosphate (Pi), that is often limited due to the formation of sparingly soluble complexes in soil; on the other hand, overapplication of phosphate fertilizer generally leads to the problems of eutrophication (diCenzo et al., 2017). Phosphorus usually occurs in vivo as free Pi or forming esters or diesters in metabolites and macromolecules. Protein phosphorylation also controls major metabolic pathways and cell division cycle (Li et al., 2016). Phosphate anion can react with another, releasing a molecule of water and producing a dimer, pyrophosphate (PPi, P2O 4− 7 ). More Pi residues may be added to PPi by means of this linkage, known as a “phosphoanhydride bond,” thus producing polyphosphate (polyP). Hydrolysis of phosphoanhydride bonds is thermodynamically favorable and kinetically slow, consequently, PPi and polyP are used for energy transfer and storage in many organisms. PPi and polyP also participate in metabolites like nucleoside triphosphate, inositol pyrophosphate, or activated isoprene.