analytical evaluation of the ratio between injection and space charge limited currents in single carrier organic diodes

An analytical, complete framework to describe the current-voltage (I-V) characteristics of organic diodes without the use of previous approaches, such as injection or bulk-limited conduction is proposed. Analytical expressions to quantify the ratio between injection and space-charge-limited current...

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Detalles Bibliográficos
Autores: ALvarez, Angel Luis, Arredondo, Belén, Romero, Beatriz, Quintana, Xabier, Gutiérrez, Araceli, Mallavia, Ricardo, Otón, José Manuel
Tipo de recurso: artículo
Fecha de publicación:2008
País:España
Institución:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/12051
Acceso en línea:http://hdl.handle.net/10115/12051
Access Level:acceso abierto
Palabra clave:hopping transport
injection current
polymer light-emitting diode (PLED)
space charge
3307 Tecnología Electrónica
3306.02 Aplicaciones Eléctricas
3307.09 Dispositivos Fotoeléctricos
Descripción
Sumario:An analytical, complete framework to describe the current-voltage (I-V) characteristics of organic diodes without the use of previous approaches, such as injection or bulk-limited conduction is proposed. Analytical expressions to quantify the ratio between injection and space-charge-limited current from experimental I-V characteristics in organic diodes have been derived. These are used to propose a numerical model in which both bulk transport and injection mechanisms are considered simultaneously. This procedure leads to a significant reduction in computing time with respect to previous rigorous numerical models. In order to test the model, different diode structures based on two different polymers: poly(2-methoxy-5-{3',7'-dimethyloetyloxy}-p-phenylenevinylene) (MDMO-PPV) and a derivative of the poly(2,7-fluorene phenylidene) [PFP:(CN)(2)], have been fabricated. The present model is excellently fitted to experimental curves and yields the microscopic parameters that characterize the active layer.