Optical dipolar chiral sorting forces and their manifestation in evanescent waves and nanofibers

[EN] Optical fields can exert forces of chiral nature on molecules and nanoparticles, which would prove extremely valuable in the separation of enantiomers with pharmaceutical applications, yet it is inherently complex, and the varied frameworks used in the literature further complicate the theoreti...

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Detalles Bibliográficos
Autores: Golat, Sebastian, Kingsley-Smith, Jack J., Rodríguez-Fortuño, Francisco J., Rodriguez-Díez, Iago|||0000-0001-8336-7438, Martínez-Romeu, Josep, Martínez, Alejandro|||0000-0001-5448-0140
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/220655
Acceso en línea:https://riunet.upv.es/handle/10251/220655
Access Level:acceso abierto
Palabra clave:Chirality
Optical forces
Evanescent wave
Nanofiber
Descripción
Sumario:[EN] Optical fields can exert forces of chiral nature on molecules and nanoparticles, which would prove extremely valuable in the separation of enantiomers with pharmaceutical applications, yet it is inherently complex, and the varied frameworks used in the literature further complicate the theoretical understanding. This paper unifies existing approaches used to describe dipolar optical forces and introduces a symmetry-based ¿force basis¿ consisting of twelve vector fields, each weighted by particle-specific coefficients, for a streamlined description of force patterns. The approach is rigorously applied to evanescent waves and dielectric nanofibers, yielding concise analytical expressions for optical forces. Through this, we identify optimal strategies for enantiomer separation, offering invaluable guidance for future experiments.