Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles

Mesoscale self-assembly of particles into supercrystals is important for the design of functional materials such as photonic and plasmonic crystals. However, while much progress has been made in self-assembling supercrystals adopting diverse lattices and using different types of particles, controlli...

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Autores: Avci, Civan|||0000-0001-7202-7454, Liu, Yang, Pariente, Jose Angel|||0000-0003-2649-9164, Blanco, Alvaro|||0000-0002-0015-4873, Lopez, Cefe, Imaz, Inhar|||0000-0002-0278-1141, Maspoch Comamala, Daniel|||0000-0003-1325-9161
Formato: artículo
Fecha de publicación:2019
País:España
Recursos:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:232154
Acesso em linha:https://ddd.uab.cat/record/232154
https://dx.doi.org/urn:doi:10.1002/smll.201902520
Access Level:acceso abierto
Palavra-chave:Metal-Organic Framework
Mesoscale assembly
Supercrystal
Crystal orientation
Photonic crystals
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spelling Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particlesAvci, Civan|||0000-0001-7202-7454Liu, YangPariente, Jose Angel|||0000-0003-2649-9164Blanco, Alvaro|||0000-0002-0015-4873Lopez, CefeImaz, Inhar|||0000-0002-0278-1141Maspoch Comamala, Daniel|||0000-0003-1325-9161Metal-Organic FrameworkMesoscale assemblySupercrystalCrystal orientationPhotonic crystalsMesoscale self-assembly of particles into supercrystals is important for the design of functional materials such as photonic and plasmonic crystals. However, while much progress has been made in self-assembling supercrystals adopting diverse lattices and using different types of particles, controlling their growth orientation on surfaces has received limited success. Most of the latter orientation control has been achieved via templating methods in which lithographic processes are used to form a patterned surface that acts as a template for particle assembly. Herein, a template-free method to self-assemble (111)-, (100)-, and (110)-oriented face-centered cubic supercrystals of the metal-organic framework ZIF-8 particles by adjusting the amount of surfactant (cetyltrimethylammonium bromide) used is described. It is shown that these supercrystals behave as photonic crystals whose properties depend on their growth orientation. This control on the orientation of the supercrystals dictates the orientation of the composing porous particles that might ultimately facilitate pore orientation on surfaces for designing membranes and sensors. 22019-01-0120192019-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/232154https://dx.doi.org/urn:doi:10.1002/smll.201902520reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengEuropean Commission https://doi.org/10.13039/501100000780 615954Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 RTI2018-095622-B-I00Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-65354-C2-1-RMinisterio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-68075-RAgència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2014/SGR-80open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2321542026-06-06T12:50:31Z
dc.title.none.fl_str_mv Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
title Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
spellingShingle Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
Avci, Civan|||0000-0001-7202-7454
Metal-Organic Framework
Mesoscale assembly
Supercrystal
Crystal orientation
Photonic crystals
title_short Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
title_full Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
title_fullStr Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
title_full_unstemmed Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
title_sort Template-free, surfactant-mediated orientation of self-assembled supercrystals of metal-organic framework particles
dc.creator.none.fl_str_mv Avci, Civan|||0000-0001-7202-7454
Liu, Yang
Pariente, Jose Angel|||0000-0003-2649-9164
Blanco, Alvaro|||0000-0002-0015-4873
Lopez, Cefe
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author Avci, Civan|||0000-0001-7202-7454
author_facet Avci, Civan|||0000-0001-7202-7454
Liu, Yang
Pariente, Jose Angel|||0000-0003-2649-9164
Blanco, Alvaro|||0000-0002-0015-4873
Lopez, Cefe
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author_role author
author2 Liu, Yang
Pariente, Jose Angel|||0000-0003-2649-9164
Blanco, Alvaro|||0000-0002-0015-4873
Lopez, Cefe
Imaz, Inhar|||0000-0002-0278-1141
Maspoch Comamala, Daniel|||0000-0003-1325-9161
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Metal-Organic Framework
Mesoscale assembly
Supercrystal
Crystal orientation
Photonic crystals
topic Metal-Organic Framework
Mesoscale assembly
Supercrystal
Crystal orientation
Photonic crystals
description Mesoscale self-assembly of particles into supercrystals is important for the design of functional materials such as photonic and plasmonic crystals. However, while much progress has been made in self-assembling supercrystals adopting diverse lattices and using different types of particles, controlling their growth orientation on surfaces has received limited success. Most of the latter orientation control has been achieved via templating methods in which lithographic processes are used to form a patterned surface that acts as a template for particle assembly. Herein, a template-free method to self-assemble (111)-, (100)-, and (110)-oriented face-centered cubic supercrystals of the metal-organic framework ZIF-8 particles by adjusting the amount of surfactant (cetyltrimethylammonium bromide) used is described. It is shown that these supercrystals behave as photonic crystals whose properties depend on their growth orientation. This control on the orientation of the supercrystals dictates the orientation of the composing porous particles that might ultimately facilitate pore orientation on surfaces for designing membranes and sensors.
publishDate 2019
dc.date.none.fl_str_mv 2
2019-01-01
2019
2019-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/232154
https://dx.doi.org/urn:doi:10.1002/smll.201902520
url https://ddd.uab.cat/record/232154
https://dx.doi.org/urn:doi:10.1002/smll.201902520
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission https://doi.org/10.13039/501100000780 615954
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 RTI2018-095622-B-I00
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-65354-C2-1-R
Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 MAT2015-68075-R
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2014/SGR-80
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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