Vibrationally resolved B 1s photoionization cross section of BF3
We present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 molecule. A combination of high-resolution photoelectron spectroscopy measurements and of state-of-the-art calculations shows the evolution of the photon energy dependence of the cross section from a compl...
| Autores: | , , , , , , , , , , , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Recursos: | Universidad Autónoma de Madrid |
| Repositorio: | Biblos-e Archivo. Repositorio Institucional de la UAM |
| Idioma: | inglés |
| OAI Identifier: | oai:repositorio.uam.es:10486/672748 |
| Acesso em linha: | http://hdl.handle.net/10486/672748 https://dx.doi.org/10.1088/1742-6596/635/11/112134 |
| Access Level: | acceso abierto |
| Palavra-chave: | Ionization Molecules Negative ions Photoelectron spectroscopy Química |
| Resumo: | We present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 molecule. A combination of high-resolution photoelectron spectroscopy measurements and of state-of-the-art calculations shows the evolution of the photon energy dependence of the cross section from a complete trapping of the photoelectron wave (low energies) to oscillations due to intramolecular scattering. These diffraction patterns allow to access structural information of both the neutral molecule and the core -hole species generated upon photoabsoption |
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