Development of a TiNbTaMoZr-Based High Entropy Alloy with Low Young´s Modulus by Mechanical Alloying Route

In this work, an equiatomic TiNbTaMoZr-based high-entropy alloy (HEA) has been developed by a powder metallurgy route, which consists of a process of combined one-step low-temperature mechanical milling starting from the transition metals as raw materials and a subsequent pressureless sintering. In...

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Detalles Bibliográficos
Autores: Normand, Juliette, Moriche Tirado, Rocío, García Garrido, Cristina, Sepúlveda Ferrer, Ranier Enrique, Chicardi Augusto, Ernesto
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2020
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/129863
Acceso en línea:https://hdl.handle.net/11441/129863
https://doi.org/10.3390/met10111463
Access Level:acceso abierto
Palabra clave:High-entropy alloys
Titanium
Biomaterials
Bone tissue engineering
Mechanical alloying
Young’s modulus
Descripción
Sumario:In this work, an equiatomic TiNbTaMoZr-based high-entropy alloy (HEA) has been developed by a powder metallurgy route, which consists of a process of combined one-step low-temperature mechanical milling starting from the transition metals as raw materials and a subsequent pressureless sintering. In this way, the optimized synthesized specimen, after 10 h of milling time, showed two di erent body-centered cubic (bcc) TiNbTaMoZr alloys, which, after sintering at 1450 C, 1 h of dwell time and a heating and cooling rate of 5 C min-1, it remained formed as two bcc TiNbTaMoZr-based HEAs. This material, with micrometric and equiaxed particles, and with homogeneously distributed phases, presented a Young’s modulus that was significantly higher (5.8 GPa) and lower (62.1 GPa) than that of the usual commercially pure (cp) Ti and Ti6Al4V alloy used for bone-replacement implants. It also presented similar values to those of the HEAs developed for the same purpose. These interesting properties would enable this TiNbTaMoZr-based HEA to be used as a potential biomaterial for bulk or porous bone implants with high hardness and low Young´s modulus, thereby preventing the appearance of stress-shielding phenomena