Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes

This article reports the high performance of a solid polymer electrolyte cell, equipped with a Nafion® N117 membrane packed between a Nb/boron‐doped diamond (Nb/BDD) mesh anode and a Ti/RuO2 mesh cathode, to degrade the insecticide imidacloprid spiked at 1.2-59.2 mg L−1 into low conductivity groundw...

Descripción completa

Detalles Bibliográficos
Autores: Oriol, Roger, Clematis, Davide, Brillas, Enric, Cortina Pallàs, José Luis, Panizza, Marco, Sirés Sadornil, Ignacio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/147637
Acceso en línea:https://hdl.handle.net/2445/147637
Access Level:acceso abierto
Palabra clave:Depuració de l'aigua
Hidrologia d'aigües subterrànies
Oxidació electroquímica
Water purification
Groundwater hydrology
Electrolytic oxidation
id ES_93d379299b6afc0cd5a49efeaa04bc77
oai_identifier_str oai:recercat.cat:2445/147637
network_acronym_str ES
network_name_str España
repository_id_str
spelling Groundwater treatment using a solid polymer electrolyte cell with mesh electrodesOriol, RogerClematis, DavideBrillas, EnricCortina Pallàs, José LuisPanizza, MarcoSirés Sadornil, IgnacioDepuració de l'aiguaHidrologia d'aigües subterràniesOxidació electroquímicaWater purificationGroundwater hydrologyElectrolytic oxidationThis article reports the high performance of a solid polymer electrolyte cell, equipped with a Nafion® N117 membrane packed between a Nb/boron‐doped diamond (Nb/BDD) mesh anode and a Ti/RuO2 mesh cathode, to degrade the insecticide imidacloprid spiked at 1.2-59.2 mg L−1 into low conductivity groundwater by electrochemical oxidation. The natural water matrix was first softened using valorized industrial waste in the form of zeolite as reactive sorbent. Total removal of the insecticide, always obeying pseudo‐first‐order kinetics, and maximum mineralization degrees of 70 %-87 % were achieved, with energy consumption of 26.4±1.6 kWh m−3. Active chlorine in the bulk and .OH at the BDD surface were the main oxidants. Comparative studies using simulated water with analogous anions content revealed that the natural organic matter interfered in the groundwater treatment. Trials carried out in ultrapure water showed the primary conversion of the initial N and Cl atoms of imidacloprid to NO3− and Cl− ions, being the latter anion eventually transformed into ClO3− and ClO4− ions. 6‐Chloro‐nicotinonitrile, 6‐chloro‐pyridine‐3‐carbaldehyde, and tartaric acid were identified as oxidation productWiley-VCH2020202020192020info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion9 p.application/pdfhttps://hdl.handle.net/2445/147637Articles publicats en revistes (Ciència dels Materials i Química Física)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésVersió postprint del document publicat a: https://doi.org/10.1002/celc.201801906ChemElectroChem, 2019, vol. 6, num. 4, p. 1235-1243https://doi.org/10.1002/celc.201801906(c) Wiley-VCH, 2019info:eu-repo/semantics/openAccessoai:recercat.cat:2445/1476372026-05-29T05:05:01Z
dc.title.none.fl_str_mv Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
title Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
spellingShingle Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
Oriol, Roger
Depuració de l'aigua
Hidrologia d'aigües subterrànies
Oxidació electroquímica
Water purification
Groundwater hydrology
Electrolytic oxidation
title_short Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
title_full Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
title_fullStr Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
title_full_unstemmed Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
title_sort Groundwater treatment using a solid polymer electrolyte cell with mesh electrodes
dc.creator.none.fl_str_mv Oriol, Roger
Clematis, Davide
Brillas, Enric
Cortina Pallàs, José Luis
Panizza, Marco
Sirés Sadornil, Ignacio
author Oriol, Roger
author_facet Oriol, Roger
Clematis, Davide
Brillas, Enric
Cortina Pallàs, José Luis
Panizza, Marco
Sirés Sadornil, Ignacio
author_role author
author2 Clematis, Davide
Brillas, Enric
Cortina Pallàs, José Luis
Panizza, Marco
Sirés Sadornil, Ignacio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Depuració de l'aigua
Hidrologia d'aigües subterrànies
Oxidació electroquímica
Water purification
Groundwater hydrology
Electrolytic oxidation
topic Depuració de l'aigua
Hidrologia d'aigües subterrànies
Oxidació electroquímica
Water purification
Groundwater hydrology
Electrolytic oxidation
description This article reports the high performance of a solid polymer electrolyte cell, equipped with a Nafion® N117 membrane packed between a Nb/boron‐doped diamond (Nb/BDD) mesh anode and a Ti/RuO2 mesh cathode, to degrade the insecticide imidacloprid spiked at 1.2-59.2 mg L−1 into low conductivity groundwater by electrochemical oxidation. The natural water matrix was first softened using valorized industrial waste in the form of zeolite as reactive sorbent. Total removal of the insecticide, always obeying pseudo‐first‐order kinetics, and maximum mineralization degrees of 70 %-87 % were achieved, with energy consumption of 26.4±1.6 kWh m−3. Active chlorine in the bulk and .OH at the BDD surface were the main oxidants. Comparative studies using simulated water with analogous anions content revealed that the natural organic matter interfered in the groundwater treatment. Trials carried out in ultrapure water showed the primary conversion of the initial N and Cl atoms of imidacloprid to NO3− and Cl− ions, being the latter anion eventually transformed into ClO3− and ClO4− ions. 6‐Chloro‐nicotinonitrile, 6‐chloro‐pyridine‐3‐carbaldehyde, and tartaric acid were identified as oxidation product
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/147637
url https://hdl.handle.net/2445/147637
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1002/celc.201801906
ChemElectroChem, 2019, vol. 6, num. 4, p. 1235-1243
https://doi.org/10.1002/celc.201801906
dc.rights.none.fl_str_mv (c) Wiley-VCH, 2019
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Wiley-VCH, 2019
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9 p.
application/pdf
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv Articles publicats en revistes (Ciència dels Materials i Química Física)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869413629740187648
score 15.198674

Similares en LA Referencia