A new type of doubly silylamido-bridged cyclopentadienyl group 4 metal complexes
Doubly bridged di(silyl-η-amido)cyclopentadienyltitanium and -zirconium complexes and their related cations as the [(PhCH 2)B(C 6F 5) 3] - salts have been isolated (see structure of the Ti derivative). The neutral benzylzirconium complex was a very efficient catalyst in the presence of methylalumino...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2001 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4202 |
| Acceso en línea: | http://hdl.handle.net/10017/4202 https://dx.doi.org/10.1002/1521-3757(20010702)113:13<2563 |
| Access Level: | acceso abierto |
| Palabra clave: | Doubly silylamido-bridged cyclopentadienyl group 4 metal Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | Doubly bridged di(silyl-η-amido)cyclopentadienyltitanium and -zirconium complexes and their related cations as the [(PhCH 2)B(C 6F 5) 3] - salts have been isolated (see structure of the Ti derivative). The neutral benzylzirconium complex was a very efficient catalyst in the presence of methylaluminoxane for producing high molecular weight polyethylene and ethylene-1-hexene copolymers |
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