Giant bulk photovoltaic effect in solar cell architectures with ultra-wide bandgap Ga2O3 transparent conducting electrodes

The use of ultra-wide bandgap transparent conducting beta gallium oxide (β-GaO) thin films as electrodes in ferroelectric solar cells is reported. In a new material structure for energy applications, we report a solar cell structure (a light absorber sandwiched in between two electrodes - one of the...

Descripción completa

Detalles Bibliográficos
Autores: Perez-Tomas, Amador|||0000-0002-0551-3142, Chikoidze, Ekaterine|||0000-0002-6566-4639, Dumont, Yves|||0000-0002-0739-428X, Jennings, M. R., Russell, Stephen A. O., Vales Castro, Pablo|||0000-0001-9181-1789, Catalan, Gustau|||0000-0003-0214-4828, Lira-Cantu, Monica|||0000-0002-3393-7436, Ton-That, C., Teherani, Féréchteh Hosseini, Sandana, Vinod E., Bove, Philippe, Rogers, David J.
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:220640
Acceso en línea:https://ddd.uab.cat/record/220640
https://dx.doi.org/urn:doi:10.1016/j.mtener.2019.100350
Access Level:acceso abierto
Palabra clave:Ultra-wide bandgap semiconductors
Transparent conducting oxide
Gallium oxide
Ga2O3
Ferroelectric photovoltaics
Pb(Zr,Ti)O3
Bulk photovoltaic effect
Solar cell architecture
Descripción
Sumario:The use of ultra-wide bandgap transparent conducting beta gallium oxide (β-GaO) thin films as electrodes in ferroelectric solar cells is reported. In a new material structure for energy applications, we report a solar cell structure (a light absorber sandwiched in between two electrodes - one of them - transparent) which is not constrained by the Shockley-Queisser limit for open-circuit voltage (V) under typical indoor light. The solar blindness of the electrode enables a record-breaking bulk photovoltaic effect (BPE) with white light illumination (general use indoor light). This work opens up the perspective of ferroelectric photovoltaics which are not subject to the Shockley-Queisser limit by bringing into scene solar-blind conducting oxides.