Copper-catalyzed O-alkenylation of phosphonates

Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phos...

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Detalles Bibliográficos
Autores: Vázquez Galiñanes, Nuria, Andón Rodríguez, Mariña, Gómez Roibás, Patricia, Fañanás-Mastral, Martín
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/21780
Acceso en línea:http://hdl.handle.net/10347/21780
Access Level:acceso abierto
Descripción
Sumario:Copper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields.