Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification

Polymeric membrane cascades have demonstrated their technical and economic viability for hydrogen peroxide ultrapurification. Nevertheless, these membranes suffer from fast degradation under such oxidative conditions. Alternative membranes with higher chemical resistance could improve the ultrapurif...

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Detalhes bibliográficos
Autores: Abejón Elías, Ricardo|||0000-0002-8030-7752, Abejón Elias, Azucena, Puthai, Waravut, Ibrahim, S.B., Nagasawa, Hiroki, Tsuru, Toshinori, Garea Vázquez, Aurora|||0000-0002-6356-4298
Formato: artículo
Fecha de publicación:2017
País:España
Recursos:Universidad de Cantabria (UC)
Repositorio:UCrea Repositorio Abierto de la Universidad de Cantabria
Idioma:inglés
OAI Identifier:oai:repositorio.unican.es:10902/11584
Acesso em linha:http://hdl.handle.net/10902/11584
Access Level:acceso abierto
Palavra-chave:Organosilica membrane
Ceramic membrane
Ultrapurification
Hydrogen peroxide
Membrane cascade
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spelling Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurificationAbejón Elías, Ricardo|||0000-0002-8030-7752Abejón Elias, AzucenaPuthai, WaravutIbrahim, S.B.Nagasawa, HirokiTsuru, ToshinoriGarea Vázquez, Aurora|||0000-0002-6356-4298Organosilica membraneCeramic membraneUltrapurificationHydrogen peroxideMembrane cascadePolymeric membrane cascades have demonstrated their technical and economic viability for hydrogen peroxide ultrapurification. Nevertheless, these membranes suffer from fast degradation under such oxidative conditions. Alternative membranes with higher chemical resistance could improve the ultrapurification process. Therefore, this work presents the preliminary techno-economic analysis of two non-commercial membranes (a ceramic one and a hybrid organosilica one). This analysis is complemented with further research regarding the competitiveness of these alternative membranes compared to polymeric ones. The results confirm the technical viability for both membranes, but the ceramic membrane is not appropriate when Na is considered as the limiting impurity (because it has too low rejection coefficient). The economic viability of the proposed ultrapurification processes is also probed, but not under competitive conditions, as the polyamide membrane appears to be the optimal choice. Nonetheless, improvements in the permeability of the hybrid membrane (an increase in the membrane permeability by a factor of 10) or the rejection performance of the ceramic membrane (an increase in the reflection coefficient above 0.85) could transform these non-commercial membranes into the most profitable alternative.This research has been financially supported by the Spanish Ministry of Economy and Competitiveness (MINECO) through CTQ2014-56820-JIN Project, co-financed by FEDER funds. R. Abejón acknowledges the assistance of the Japan Society for Promotion of Science (JSPS) for the award of a Post-Doctoral Fellowship (Short-Term) for North American and European Researchers (PE14057).Institution of Chemical EngineersUniversidad de Cantabria20172017-09-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articlehttp://hdl.handle.net/10902/11584Chemical Engineering Research and Design, 2017, 125, 385-397reponame:UCrea Repositorio Abierto de la Universidad de Cantabriainstname:Universidad de Cantabria (UC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:repositorio.unican.es:10902/115842026-06-02T12:39:31Z
dc.title.none.fl_str_mv Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
title Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
spellingShingle Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
Abejón Elías, Ricardo|||0000-0002-8030-7752
Organosilica membrane
Ceramic membrane
Ultrapurification
Hydrogen peroxide
Membrane cascade
title_short Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
title_full Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
title_fullStr Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
title_full_unstemmed Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
title_sort Preliminary techno-economic analysis of non-commercial ceramic and organosilica membranes for hydrogen peroxide ultrapurification
dc.creator.none.fl_str_mv Abejón Elías, Ricardo|||0000-0002-8030-7752
Abejón Elias, Azucena
Puthai, Waravut
Ibrahim, S.B.
Nagasawa, Hiroki
Tsuru, Toshinori
Garea Vázquez, Aurora|||0000-0002-6356-4298
author Abejón Elías, Ricardo|||0000-0002-8030-7752
author_facet Abejón Elías, Ricardo|||0000-0002-8030-7752
Abejón Elias, Azucena
Puthai, Waravut
Ibrahim, S.B.
Nagasawa, Hiroki
Tsuru, Toshinori
Garea Vázquez, Aurora|||0000-0002-6356-4298
author_role author
author2 Abejón Elias, Azucena
Puthai, Waravut
Ibrahim, S.B.
Nagasawa, Hiroki
Tsuru, Toshinori
Garea Vázquez, Aurora|||0000-0002-6356-4298
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad de Cantabria
dc.subject.none.fl_str_mv Organosilica membrane
Ceramic membrane
Ultrapurification
Hydrogen peroxide
Membrane cascade
topic Organosilica membrane
Ceramic membrane
Ultrapurification
Hydrogen peroxide
Membrane cascade
description Polymeric membrane cascades have demonstrated their technical and economic viability for hydrogen peroxide ultrapurification. Nevertheless, these membranes suffer from fast degradation under such oxidative conditions. Alternative membranes with higher chemical resistance could improve the ultrapurification process. Therefore, this work presents the preliminary techno-economic analysis of two non-commercial membranes (a ceramic one and a hybrid organosilica one). This analysis is complemented with further research regarding the competitiveness of these alternative membranes compared to polymeric ones. The results confirm the technical viability for both membranes, but the ceramic membrane is not appropriate when Na is considered as the limiting impurity (because it has too low rejection coefficient). The economic viability of the proposed ultrapurification processes is also probed, but not under competitive conditions, as the polyamide membrane appears to be the optimal choice. Nonetheless, improvements in the permeability of the hybrid membrane (an increase in the membrane permeability by a factor of 10) or the rejection performance of the ceramic membrane (an increase in the reflection coefficient above 0.85) could transform these non-commercial membranes into the most profitable alternative.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-09-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10902/11584
url http://hdl.handle.net/10902/11584
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Institution of Chemical Engineers
publisher.none.fl_str_mv Institution of Chemical Engineers
dc.source.none.fl_str_mv Chemical Engineering Research and Design, 2017, 125, 385-397
reponame:UCrea Repositorio Abierto de la Universidad de Cantabria
instname:Universidad de Cantabria (UC)
instname_str Universidad de Cantabria (UC)
reponame_str UCrea Repositorio Abierto de la Universidad de Cantabria
collection UCrea Repositorio Abierto de la Universidad de Cantabria
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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