Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery

[EN] Expanders, as lignosulfonates, are crucial for a good performance of Pb/acid batteries. In the process of discharge, the Pb and the PbO go to PbSO. The formed PbSO is adsorbed on the surface of the Pb electrode and dramatically reduces the lifetime of the battery by the formation of big PbSO cr...

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Autores: Tghos Naim, Maryame, Lara-Serrano, Marta, Romero, Alberto F., Morales-delaRosa, Silvia, Campos Martín, José Miguel, Avilés Moreno, J. Ramón, Ocón, Pilar
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/297157
Acceso en línea:http://hdl.handle.net/10261/297157
Access Level:acceso abierto
Palabra clave:Lignin
Lignosulfonate
Additives
Lead acid batteries
Physicochemical characterization
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spelling Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid batteryTghos Naim, MaryameLara-Serrano, MartaRomero, Alberto F.Morales-delaRosa, SilviaCampos Martín, José MiguelAvilés Moreno, J. RamónOcón, PilarLigninLignosulfonateAdditivesLead acid batteriesPhysicochemical characterization[EN] Expanders, as lignosulfonates, are crucial for a good performance of Pb/acid batteries. In the process of discharge, the Pb and the PbO go to PbSO. The formed PbSO is adsorbed on the surface of the Pb electrode and dramatically reduces the lifetime of the battery by the formation of big PbSO crystals. In order to prevent that, the addition of expanders in the negative electrode is an economic solution to prevent the formation of big crystals. In this investigation, we propose the synthesis of several lignosulfonates obtained from lignin of many biomass origins. We have derivatized nine samples of lignin via microwave-assisted sulfonation, then we have characterized how efficient is the chosen synthesis method. The lignosulfonates obtained have been characterized by infrared spectroscopy (IR), proton nuclear magnetic resonance (HNMR), two-dimensional correlated spectroscopy (COSY), and elemental analysis to acquire some relevant information about their structure in terms of functional groups. In this way, three commercial lignosulfonates, Vanisperse A, Indulin AT, and Oakwood, have been selected as references for our comparisons. Moreover, we have checked their electrochemical properties, using electrochemical techniques to compare their behavior with respect to the commercial lignosulfonates. Finally, we have selected one of them and we have tested its performance as an expander in a Pb/acid battery. That result is a very promising first approach, and we can conclude that lignosulfonates derivatives are a good and low-cost choice to improve the lifetime of Pb/acid batteries. In particular, it is shown that the incorporation of LignosB improves the cell formation as well as the first capacity (36.30% more) and the charge acceptance (63.16% more), being these relevant parameters in the performance of Pb/acid batteries.Comunidad de Madrid (Spain) and ERDF (European Regional Development Fund), grant number S2018/EMT-4344 (BIOTRES-CM) and Grant PID2020-112594RB-C33 funded by MCIN/AEI/10 13039/501100011033Elsevier BVComunidad de MadridAgencia Estatal de Investigación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2023202320222023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/297157reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112594RB-C33S2018/EMT-4344/BIOTRES-CMhttp://dx.doi.org/10.1016/j.arabjc.2022.104127Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2971572026-05-22T06:33:51Z
dc.title.none.fl_str_mv Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
title Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
spellingShingle Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
Tghos Naim, Maryame
Lignin
Lignosulfonate
Additives
Lead acid batteries
Physicochemical characterization
title_short Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
title_full Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
title_fullStr Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
title_full_unstemmed Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
title_sort Characterization of lignin and lignin-derivatives from biomass. Application as expander of Lead-acid battery
dc.creator.none.fl_str_mv Tghos Naim, Maryame
Lara-Serrano, Marta
Romero, Alberto F.
Morales-delaRosa, Silvia
Campos Martín, José Miguel
Avilés Moreno, J. Ramón
Ocón, Pilar
author Tghos Naim, Maryame
author_facet Tghos Naim, Maryame
Lara-Serrano, Marta
Romero, Alberto F.
Morales-delaRosa, Silvia
Campos Martín, José Miguel
Avilés Moreno, J. Ramón
Ocón, Pilar
author_role author
author2 Lara-Serrano, Marta
Romero, Alberto F.
Morales-delaRosa, Silvia
Campos Martín, José Miguel
Avilés Moreno, J. Ramón
Ocón, Pilar
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Comunidad de Madrid
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Lignin
Lignosulfonate
Additives
Lead acid batteries
Physicochemical characterization
topic Lignin
Lignosulfonate
Additives
Lead acid batteries
Physicochemical characterization
description [EN] Expanders, as lignosulfonates, are crucial for a good performance of Pb/acid batteries. In the process of discharge, the Pb and the PbO go to PbSO. The formed PbSO is adsorbed on the surface of the Pb electrode and dramatically reduces the lifetime of the battery by the formation of big PbSO crystals. In order to prevent that, the addition of expanders in the negative electrode is an economic solution to prevent the formation of big crystals. In this investigation, we propose the synthesis of several lignosulfonates obtained from lignin of many biomass origins. We have derivatized nine samples of lignin via microwave-assisted sulfonation, then we have characterized how efficient is the chosen synthesis method. The lignosulfonates obtained have been characterized by infrared spectroscopy (IR), proton nuclear magnetic resonance (HNMR), two-dimensional correlated spectroscopy (COSY), and elemental analysis to acquire some relevant information about their structure in terms of functional groups. In this way, three commercial lignosulfonates, Vanisperse A, Indulin AT, and Oakwood, have been selected as references for our comparisons. Moreover, we have checked their electrochemical properties, using electrochemical techniques to compare their behavior with respect to the commercial lignosulfonates. Finally, we have selected one of them and we have tested its performance as an expander in a Pb/acid battery. That result is a very promising first approach, and we can conclude that lignosulfonates derivatives are a good and low-cost choice to improve the lifetime of Pb/acid batteries. In particular, it is shown that the incorporation of LignosB improves the cell formation as well as the first capacity (36.30% more) and the charge acceptance (63.16% more), being these relevant parameters in the performance of Pb/acid batteries.
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/297157
url http://hdl.handle.net/10261/297157
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112594RB-C33
S2018/EMT-4344/BIOTRES-CM
http://dx.doi.org/10.1016/j.arabjc.2022.104127
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier BV
publisher.none.fl_str_mv Elsevier BV
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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