Non-heteroatom-substituted alkylidene complexes of groups 10 and 11

This review aims to offer a detailed summary of the discoveries regarding non-heteroatom-substituted alkylidenes of group 10 and 11 metals that have appeared in the literature since the first isolable representative of this class was reported in 2002. Special attention is focused on synthetic and bo...

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Detalles Bibliográficos
Autores: Peloso, Riccardo, Carmona, Ernesto
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/177347
Acceso en línea:http://hdl.handle.net/10261/177347
Access Level:acceso abierto
Palabra clave:Alkylidenes
Organometallic chemistry
Group 10 metals
Group 11 metals.
Carbenes
Descripción
Sumario:This review aims to offer a detailed summary of the discoveries regarding non-heteroatom-substituted alkylidenes of group 10 and 11 metals that have appeared in the literature since the first isolable representative of this class was reported in 2002. Special attention is focused on synthetic and bonding aspects of well-defined species. The importance of this family of compounds in catalytic organic transformations is often mentioned and a number of references are provided. We stress, however, that it is not the main issue of this review, as this topic has received considerable attention in the current literature.