Dynamic mechanical relaxation behavior of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass

Non-equiatomic high entropy bulk metallic glasses were reported recently and show unique mechanical and physical properties. Dynamic mechanical relaxation behavior of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass was investigated by dynamic mechanical analysis (DMA) and the mec...

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Bibliographic Details
Authors: Zhang, L.T., Duan, Y.J., Wada, T., Kato, Hidemi, Pelletier, J. M., Crespo Artiaga, Daniel|||0000-0003-1743-2400, Pineda Soler, Eloi|||0000-0002-1871-3848, Qiao, J. C.
Format: article
Publication Date:2021
Country:España
Institution:Universitat Politècnica de Catalunya (UPC)
Repository:UPCommons. Portal del coneixement obert de la UPC
Language:English
OAI Identifier:oai:upcommons.upc.edu:2117/347863
Online Access:https://hdl.handle.net/2117/347863
https://dx.doi.org/10.1016/j.jmst.2020.11.074
Access Level:Open access
Keyword:Metallic glasses
High entropy bulk metallic glass
Mechanical relaxation
Quasi-point defects
Physical aging
Vidres metàl·lics
Àrees temàtiques de la UPC::Física
Description
Summary:Non-equiatomic high entropy bulk metallic glasses were reported recently and show unique mechanical and physical properties. Dynamic mechanical relaxation behavior of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass was investigated by dynamic mechanical analysis (DMA) and the mechanical spectra could be well described by the quasi-point defects (QPD) theory. Compared to typical metallic glasses, the intensity of the ß relaxation of Zr35Hf17.5Ti5.5Al12.5Co7.5Ni12Cu10 high entropy bulk metallic glass is lower due to the sluggish diffusion. At the same time, the correlation factor ¿ is higher than that of conventional metallic glasses and this is ascribed to the high configuration entropy. In parallel, physical aging below the glass transition temperature leads to a decrease of atomic mobility, caused by a decrease of the concentration of defects.