Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides

We have investigated by means of high-pressure x-ray diffraction the structural stability of Pd 2Mo 3N, Ni 2Mo 3C 0.52N 0.48, Co 3Mo 3C 0.62N 0.38, and Fe 3Mo 3C. We have found that they remain stable in their ambient-pressure cubic phase at least up to 48 GPa. All of them have a bulk modulus larger...

Descripción completa

Detalles Bibliográficos
Autores: Errandonea, D., Ruiz-Fuertes, J., Sans, J. A., Santamaría-Perez, D., Gómez, A., Sapiña, F., Gomis, O.|||0000-0001-6763-0638
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/47819
Acceso en línea:https://riunet.upv.es/handle/10251/47819
Access Level:acceso abierto
Palabra clave:Nitrides
Molybdenum
Pd2Mo3N
Carbides
Ultra-incompressible
Compounds
High-pressure
Structural stability
FISICA APLICADA
id ES_8f0c19202a390c30f02afdddaf5b5dc1
oai_identifier_str oai:riunet.upv.es:10251/47819
network_acronym_str ES
network_name_str España
repository_id_str
spelling Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitridesErrandonea, D.Ruiz-Fuertes, J.Sans, J. A.Santamaría-Perez, D.Gómez, A.Sapiña, F.Gomis, O.|||0000-0001-6763-0638NitridesMolybdenumPd2Mo3NCarbidesUltra-incompressibleCompoundsHigh-pressureStructural stabilityFISICA APLICADAWe have investigated by means of high-pressure x-ray diffraction the structural stability of Pd 2Mo 3N, Ni 2Mo 3C 0.52N 0.48, Co 3Mo 3C 0.62N 0.38, and Fe 3Mo 3C. We have found that they remain stable in their ambient-pressure cubic phase at least up to 48 GPa. All of them have a bulk modulus larger than 330 GPa, the least compressible material being Fe 3Mo 3C, B 0 = 374(3) GPa. In addition, apparently a reduction of compressibility is detected as the carbon content is increased. The equation of state for each material is determined. A comparison with other refractory materials indicates that interstitial nitrides and carbides behave as ultra-incompressible materials. © 2012 American Physical Society.Research supported by Spanish MCYT under Grants No. MAT2010-21270-C04-01, No. MAT2009-14144-CO3-03, and No. CSD2007-00045 (MALTA Consolider Team). XRD experiments carried out at the Diamond Light Source (I15 beamline, proposal EE6517).American Physical SocietyDepartamento de Física AplicadaEscuela Politécnica Superior de AlcoyCentro de Tecnologías Físicas: Acústica, Materiales y AstrofísicaRepositorio Institucional de la Universitat Politècnica de València Riunet20122012-04-06journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/47819reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Educación y Ciencia https://doi.org/10.13039/501100008743 CSD2007-00045 MATERIA A ALTA PRESIONMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MAT2010-21270-C04-01 SINTESIS Y CARACTERIZACION OPTICA, ELECTRONICA, ESTRUCTURAL Y VIBRACIONAL DE NUEVOS MATERIALES BAJO CONDICIONES EXTREMAS DE PRESION Y TEMPERATURAMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MAT2009-14144-C03-03 Sintesis De Materiales Nanoestructurados Para La Obtencion De Recubrimientos Por Proyeccion De Plasma Atmosferico A Partir De Disoluciones Y Suspensiones Concentradasopen accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/478192026-06-13T07:49:27Z
dc.title.none.fl_str_mv Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
title Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
spellingShingle Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
Errandonea, D.
Nitrides
Molybdenum
Pd2Mo3N
Carbides
Ultra-incompressible
Compounds
High-pressure
Structural stability
FISICA APLICADA
title_short Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
title_full Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
title_fullStr Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
title_full_unstemmed Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
title_sort Compressibility and structural stability of ultra-incompressible bimetallic interstitial carbides and nitrides
dc.creator.none.fl_str_mv Errandonea, D.
Ruiz-Fuertes, J.
Sans, J. A.
Santamaría-Perez, D.
Gómez, A.
Sapiña, F.
Gomis, O.|||0000-0001-6763-0638
author Errandonea, D.
author_facet Errandonea, D.
Ruiz-Fuertes, J.
Sans, J. A.
Santamaría-Perez, D.
Gómez, A.
Sapiña, F.
Gomis, O.|||0000-0001-6763-0638
author_role author
author2 Ruiz-Fuertes, J.
Sans, J. A.
Santamaría-Perez, D.
Gómez, A.
Sapiña, F.
Gomis, O.|||0000-0001-6763-0638
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Física Aplicada
Escuela Politécnica Superior de Alcoy
Centro de Tecnologías Físicas: Acústica, Materiales y Astrofísica
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Nitrides
Molybdenum
Pd2Mo3N
Carbides
Ultra-incompressible
Compounds
High-pressure
Structural stability
FISICA APLICADA
topic Nitrides
Molybdenum
Pd2Mo3N
Carbides
Ultra-incompressible
Compounds
High-pressure
Structural stability
FISICA APLICADA
description We have investigated by means of high-pressure x-ray diffraction the structural stability of Pd 2Mo 3N, Ni 2Mo 3C 0.52N 0.48, Co 3Mo 3C 0.62N 0.38, and Fe 3Mo 3C. We have found that they remain stable in their ambient-pressure cubic phase at least up to 48 GPa. All of them have a bulk modulus larger than 330 GPa, the least compressible material being Fe 3Mo 3C, B 0 = 374(3) GPa. In addition, apparently a reduction of compressibility is detected as the carbon content is increased. The equation of state for each material is determined. A comparison with other refractory materials indicates that interstitial nitrides and carbides behave as ultra-incompressible materials. © 2012 American Physical Society.
publishDate 2012
dc.date.none.fl_str_mv 2012
2012-04-06
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/47819
url https://riunet.upv.es/handle/10251/47819
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Educación y Ciencia https://doi.org/10.13039/501100008743 CSD2007-00045 MATERIA A ALTA PRESION
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MAT2010-21270-C04-01 SINTESIS Y CARACTERIZACION OPTICA, ELECTRONICA, ESTRUCTURAL Y VIBRACIONAL DE NUEVOS MATERIALES BAJO CONDICIONES EXTREMAS DE PRESION Y TEMPERATURA
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MAT2009-14144-C03-03 Sintesis De Materiales Nanoestructurados Para La Obtencion De Recubrimientos Por Proyeccion De Plasma Atmosferico A Partir De Disoluciones Y Suspensiones Concentradas
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Physical Society
publisher.none.fl_str_mv American Physical Society
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869413178970996736
score 15,300724

Similares en LA Referencia