Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals

Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape, were prepared by a facile, high-yield, scalable, and high-concentration heat-up procedure. The key parameters to minimize the NC size distribution were efficient mixing and heat transfer in the reaction mixture through int...

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Detalhes bibliográficos
Autores: Shavel, Alexey, Ibáñez Sabaté, Maria, Luo, Zhishan, De Roo, Jonathan, Carreté, Àlex, Dimitrievska, Mirjana, Genç, Aziz, Meyns, Michael, Pérez Rodríguez, Alejandro, Kovalenko, Maksym V., Arbiol i Cobos, Jordi, Cabot i Codina, Andreu
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Recursos:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/125077
Acesso em linha:https://hdl.handle.net/2445/125077
Access Level:acceso abierto
Palavra-chave:Química de superfícies
Nanocristalls
Nanopartícules
Termoelectricitat
Surface chemistry
Nanocrystals
Nanoparticles
Thermoelectricity
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spelling Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystalsShavel, AlexeyIbáñez Sabaté, MariaLuo, ZhishanDe Roo, JonathanCarreté, ÀlexDimitrievska, MirjanaGenç, AzizMeyns, MichaelPérez Rodríguez, AlejandroKovalenko, Maksym V.Arbiol i Cobos, JordiCabot i Codina, AndreuQuímica de superfíciesNanocristallsNanopartículesTermoelectricitatSurface chemistryNanocrystalsNanoparticlesThermoelectricityMonodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape, were prepared by a facile, high-yield, scalable, and high-concentration heat-up procedure. The key parameters to minimize the NC size distribution were efficient mixing and heat transfer in the reaction mixture through intensive argon bubbling and improved control of the heating ramp stability. Optimized synthetic conditions allowed the production of several grams of highly monodisperse CZTS NCs per batch, with up to 5 wt % concentration in a crude solution and a yield above 90%.American Chemical Society2016info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/125077Articles publicats en revistes (Enginyeria Electrònica i Biomèdica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: https://doi.org/10.1021/acs.chemmater.5b03417Chemistry of Materials, 2016, vol. 28, num. 3, p. 720-726https://doi.org/10.1021/acs.chemmater.5b03417info:eu-repo/grantAgreement/EC/FP7/284486info:eu-repo/grantAgreement/EC/FP7/306733info:eu-repo/grantAgreement/EC/FP7/316488info:eu-repo/grantAgreement/EC/FP7/310250(c) American Chemical Society , 2016info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1250772026-05-27T06:46:51Z
dc.title.none.fl_str_mv Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
title Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
spellingShingle Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
Shavel, Alexey
Química de superfícies
Nanocristalls
Nanopartícules
Termoelectricitat
Surface chemistry
Nanocrystals
Nanoparticles
Thermoelectricity
title_short Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
title_full Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
title_fullStr Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
title_full_unstemmed Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
title_sort Scalable heating-up synthesis of monodisperse Cu2ZnSnS4 nanocrystals
dc.creator.none.fl_str_mv Shavel, Alexey
Ibáñez Sabaté, Maria
Luo, Zhishan
De Roo, Jonathan
Carreté, Àlex
Dimitrievska, Mirjana
Genç, Aziz
Meyns, Michael
Pérez Rodríguez, Alejandro
Kovalenko, Maksym V.
Arbiol i Cobos, Jordi
Cabot i Codina, Andreu
author Shavel, Alexey
author_facet Shavel, Alexey
Ibáñez Sabaté, Maria
Luo, Zhishan
De Roo, Jonathan
Carreté, Àlex
Dimitrievska, Mirjana
Genç, Aziz
Meyns, Michael
Pérez Rodríguez, Alejandro
Kovalenko, Maksym V.
Arbiol i Cobos, Jordi
Cabot i Codina, Andreu
author_role author
author2 Ibáñez Sabaté, Maria
Luo, Zhishan
De Roo, Jonathan
Carreté, Àlex
Dimitrievska, Mirjana
Genç, Aziz
Meyns, Michael
Pérez Rodríguez, Alejandro
Kovalenko, Maksym V.
Arbiol i Cobos, Jordi
Cabot i Codina, Andreu
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Química de superfícies
Nanocristalls
Nanopartícules
Termoelectricitat
Surface chemistry
Nanocrystals
Nanoparticles
Thermoelectricity
topic Química de superfícies
Nanocristalls
Nanopartícules
Termoelectricitat
Surface chemistry
Nanocrystals
Nanoparticles
Thermoelectricity
description Monodisperse Cu2ZnSnS4 (CZTS) nanocrystals (NCs), with quasi-spherical shape, were prepared by a facile, high-yield, scalable, and high-concentration heat-up procedure. The key parameters to minimize the NC size distribution were efficient mixing and heat transfer in the reaction mixture through intensive argon bubbling and improved control of the heating ramp stability. Optimized synthetic conditions allowed the production of several grams of highly monodisperse CZTS NCs per batch, with up to 5 wt % concentration in a crude solution and a yield above 90%.
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/125077
url https://hdl.handle.net/2445/125077
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1021/acs.chemmater.5b03417
Chemistry of Materials, 2016, vol. 28, num. 3, p. 720-726
https://doi.org/10.1021/acs.chemmater.5b03417
info:eu-repo/grantAgreement/EC/FP7/284486
info:eu-repo/grantAgreement/EC/FP7/306733
info:eu-repo/grantAgreement/EC/FP7/316488
info:eu-repo/grantAgreement/EC/FP7/310250
dc.rights.none.fl_str_mv (c) American Chemical Society , 2016
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) American Chemical Society , 2016
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv Articles publicats en revistes (Enginyeria Electrònica i Biomèdica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.198674

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