Effects of graphene nanoplatelets and cellular structure on the thermal conductivity of polysulfone nanocomposite foams

Polysulfone (PSU) foams containing 0–10 wt% graphene nanoplatelets (GnP) were prepared using two foaming methods. Alongside the analysis of the cellular structure, their thermal conductivity was measured and analyzed. The results showed that the presence of GnP can a ect the cellular structure of th...

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Detalles Bibliográficos
Autores: Abbasi, Hooman|||0000-0001-5167-4126, Antunes, Marcelo de Sousa Pais|||0000-0001-5911-1969, Velasco Perero, José Ignacio|||0000-0003-0331-5270
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/174397
Acceso en línea:https://hdl.handle.net/2117/174397
https://dx.doi.org/10.3390/polym12010025
Access Level:acceso abierto
Palabra clave:Graphene
Foam
Plastic foams
Carbon dioxide
Thermal conductivity
Polysulfone foams
Tortuosity
Water vapor induced phase separation
scCO2
Grafè
Escuma (Química)
Escumes plàstiques
Anhídrid carbònic
Àrees temàtiques de la UPC::Enginyeria dels materials
Descripción
Sumario:Polysulfone (PSU) foams containing 0–10 wt% graphene nanoplatelets (GnP) were prepared using two foaming methods. Alongside the analysis of the cellular structure, their thermal conductivity was measured and analyzed. The results showed that the presence of GnP can a ect the cellular structure of the foams prepared by both water vapor induced phase separation (WVIPS) and supercritical CO2 (scCO2) dissolution; however, the impact is greater in the case of foams prepared by WVIPS. In terms of thermal conductivity, the analysis showed an increasing trend by incrementing the amount of GnP and increasing relative density, with the tortuosity of the cellular structure, dependent on the used foaming method, relative density, and amount of GnP, playing a key role in the final value of thermal conductivity. The combination of all these factors showed the possibility of preparing PSU-GnP foams with enhanced thermal conductivity at lower GnP amount by carefully controlling the cellular structure and relative density, opening up their use in lightweight heat dissipators