Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures

Extensively research has been devoted to the isolation and characterization of Cu(II) coordination polymers. Since many aspects can influence the final crystal structure, the effect of the solvent molecules through intermolecular interactions has been proven to be a determining factor. Herein, we el...

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Detalles Bibliográficos
Autores: Sánchez-Férez, Francisco, Calvet Pallàs, Maria Teresa, Font Bardia, Ma. Mercedes, Pons, Josefina
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/183586
Acceso en línea:https://hdl.handle.net/2445/183586
Access Level:acceso abierto
Palabra clave:Radiocristal·lografia
Compostos organometàl·lics
Estructura cristal·lina (Sòlids)
X-ray crystallography
Organometallic compounds
Layer structure (Solids)
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spelling Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structuresSánchez-Férez, FranciscoCalvet Pallàs, Maria TeresaFont Bardia, Ma. MercedesPons, JosefinaRadiocristal·lografiaCompostos organometàl·licsEstructura cristal·lina (Sòlids)X-ray crystallographyOrganometallic compoundsLayer structure (Solids)Extensively research has been devoted to the isolation and characterization of Cu(II) coordination polymers. Since many aspects can influence the final crystal structure, the effect of the solvent molecules through intermolecular interactions has been proven to be a determining factor. Herein, we elucidated the structure of two Cu(II) concomitant 1D polymers containing piperonylic acid (HPip) and 4,4 -bipyridine (4,4-bipy), which were simultaneously crystallized and subsequently isolated changing the synthetic conditions. Complex {[Cu(Pip)2(4,4-bipy)]}n (1) exhibits zig-zag polymeric chains while {[Cu(Pip)2(4,4 -bipy)(H2O)]¿ 1/2(4,4-bipy)¿(DMF)}n (2) displays linear polymeric chains stacked by water¿¿¿carboxylate intermolecular interactions, forming voids occupied by alternated guest 4,4-bipy and DMF molecules.Elsevier B.V.2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/183586Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2021.130219Journal of Molecular Structure, 2021, vol. 1235, num. 130219https://doi.org/10.1016/j.molstruc.2021.130219cc-by-nc-nd (c) Elsevier B.V., 2021https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1835862026-05-27T06:46:51Z
dc.title.none.fl_str_mv Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
title Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
spellingShingle Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
Sánchez-Férez, Francisco
Radiocristal·lografia
Compostos organometàl·lics
Estructura cristal·lina (Sòlids)
X-ray crystallography
Organometallic compounds
Layer structure (Solids)
title_short Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
title_full Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
title_fullStr Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
title_full_unstemmed Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
title_sort Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures
dc.creator.none.fl_str_mv Sánchez-Férez, Francisco
Calvet Pallàs, Maria Teresa
Font Bardia, Ma. Mercedes
Pons, Josefina
author Sánchez-Férez, Francisco
author_facet Sánchez-Férez, Francisco
Calvet Pallàs, Maria Teresa
Font Bardia, Ma. Mercedes
Pons, Josefina
author_role author
author2 Calvet Pallàs, Maria Teresa
Font Bardia, Ma. Mercedes
Pons, Josefina
author2_role author
author
author
dc.subject.none.fl_str_mv Radiocristal·lografia
Compostos organometàl·lics
Estructura cristal·lina (Sòlids)
X-ray crystallography
Organometallic compounds
Layer structure (Solids)
topic Radiocristal·lografia
Compostos organometàl·lics
Estructura cristal·lina (Sòlids)
X-ray crystallography
Organometallic compounds
Layer structure (Solids)
description Extensively research has been devoted to the isolation and characterization of Cu(II) coordination polymers. Since many aspects can influence the final crystal structure, the effect of the solvent molecules through intermolecular interactions has been proven to be a determining factor. Herein, we elucidated the structure of two Cu(II) concomitant 1D polymers containing piperonylic acid (HPip) and 4,4 -bipyridine (4,4-bipy), which were simultaneously crystallized and subsequently isolated changing the synthetic conditions. Complex {[Cu(Pip)2(4,4-bipy)]}n (1) exhibits zig-zag polymeric chains while {[Cu(Pip)2(4,4 -bipy)(H2O)]¿ 1/2(4,4-bipy)¿(DMF)}n (2) displays linear polymeric chains stacked by water¿¿¿carboxylate intermolecular interactions, forming voids occupied by alternated guest 4,4-bipy and DMF molecules.
publishDate 2021
dc.date.none.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/183586
url https://hdl.handle.net/2445/183586
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2021.130219
Journal of Molecular Structure, 2021, vol. 1235, num. 130219
https://doi.org/10.1016/j.molstruc.2021.130219
dc.rights.none.fl_str_mv cc-by-nc-nd (c) Elsevier B.V., 2021
https://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc-nd (c) Elsevier B.V., 2021
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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