Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
12th International Conference on Greenhouse Gas Control Technologies, GHGT-12
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:dnet:digitalcsic_::fdad73af221046a7a60811f6b0e7d68e |
| Acceso en línea: | http://hdl.handle.net/10261/111587 |
| Access Level: | acceso abierto |
| Palabra clave: | Biogas upgrading Biomass CO2 adsorption |
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Towards Bio-upgrading of Biogas: Biomass Waste-based AdsorbentsÁlvarez Gutiérrez, NoeliaGarcía López, SusanaGil Matellanes, María VictoriaRubiera González, FernandoPevida García, CovadongaBiogas upgradingBiomassCO2 adsorption12th International Conference on Greenhouse Gas Control Technologies, GHGT-12The choice of an appropriate adsorbent for CO2 separation by pressure swing adsorption remains a field of intense research and it would be of great help to rely on a parameter that could be used to quickly evaluate the performance of those materials. In this work, two activated carbons prepared in our laboratory from biomass wastes (olive and cherry stones) are studied for the separation of CO2 from mixtures of CO2 and CH4. CO2 and CH4 adsorption isotherms at room temperature and up to 10 bar were determined in a high pressure magnetic suspension balance. Breakthrough adsorption experiments with simulated biogas binary mixtures were conducted in a fixed-bed lab-pilot adsorption unit. The performance of the tested carbons was assessed in terms of a dimensionless sorbent selection parameter (S), which is based on the selectivity but incorporates the nature of the adsorption isotherm under PSA operating conditions. A commercial activated carbon Calgon BPL was also tested and used as reference material for the separation process. Experimental results show that the performance of the different adsorbents, based on the calculated S parameter, may be very different depending on whether data is derived from pure component adsorption isotherms or from breakthrough adsorption experiments. Under dynamic flow conditions, activated carbons produced in this study show a great potential to be applied to a CO2/CH4 separation for biogas upgrading purposes. Further research is envisioned in order to define a PSA process that maximizes the purity and recovery of CH4.Work carried out with financial support from the Spanish MINECO (Project ENE2011-23467), co-financed by the European Regional Development Fund (ERDF). N.A-G. acknowledges a fellowship from the Spanish MINECO (FPI program), co-financed by the European Social Fund.Peer reviewedElsevierConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201520152014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/111587reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1016/j.egypro.2014.11.688Síinfo:eu-repo/semantics/openAccessoai:dnet:digitalcsic_::fdad73af221046a7a60811f6b0e7d68e2026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| title |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| spellingShingle |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents Álvarez Gutiérrez, Noelia Biogas upgrading Biomass CO2 adsorption |
| title_short |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| title_full |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| title_fullStr |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| title_full_unstemmed |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| title_sort |
Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents |
| dc.creator.none.fl_str_mv |
Álvarez Gutiérrez, Noelia García López, Susana Gil Matellanes, María Victoria Rubiera González, Fernando Pevida García, Covadonga |
| author |
Álvarez Gutiérrez, Noelia |
| author_facet |
Álvarez Gutiérrez, Noelia García López, Susana Gil Matellanes, María Victoria Rubiera González, Fernando Pevida García, Covadonga |
| author_role |
author |
| author2 |
García López, Susana Gil Matellanes, María Victoria Rubiera González, Fernando Pevida García, Covadonga |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Biogas upgrading Biomass CO2 adsorption |
| topic |
Biogas upgrading Biomass CO2 adsorption |
| description |
12th International Conference on Greenhouse Gas Control Technologies, GHGT-12 |
| publishDate |
2014 |
| dc.date.none.fl_str_mv |
2014 2015 2015 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/111587 |
| url |
http://hdl.handle.net/10261/111587 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
http://dx.doi.org/10.1016/j.egypro.2014.11.688 Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869412976321101824 |
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15,812429 |