Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents

12th International Conference on Greenhouse Gas Control Technologies, GHGT-12

Detalles Bibliográficos
Autores: Álvarez Gutiérrez, Noelia, García López, Susana, Gil Matellanes, María Victoria, Rubiera González, Fernando, Pevida García, Covadonga
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:dnet:digitalcsic_::fdad73af221046a7a60811f6b0e7d68e
Acceso en línea:http://hdl.handle.net/10261/111587
Access Level:acceso abierto
Palabra clave:Biogas upgrading
Biomass
CO2 adsorption
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spelling Towards Bio-upgrading of Biogas: Biomass Waste-based AdsorbentsÁlvarez Gutiérrez, NoeliaGarcía López, SusanaGil Matellanes, María VictoriaRubiera González, FernandoPevida García, CovadongaBiogas upgradingBiomassCO2 adsorption12th International Conference on Greenhouse Gas Control Technologies, GHGT-12The choice of an appropriate adsorbent for CO2 separation by pressure swing adsorption remains a field of intense research and it would be of great help to rely on a parameter that could be used to quickly evaluate the performance of those materials. In this work, two activated carbons prepared in our laboratory from biomass wastes (olive and cherry stones) are studied for the separation of CO2 from mixtures of CO2 and CH4. CO2 and CH4 adsorption isotherms at room temperature and up to 10 bar were determined in a high pressure magnetic suspension balance. Breakthrough adsorption experiments with simulated biogas binary mixtures were conducted in a fixed-bed lab-pilot adsorption unit. The performance of the tested carbons was assessed in terms of a dimensionless sorbent selection parameter (S), which is based on the selectivity but incorporates the nature of the adsorption isotherm under PSA operating conditions. A commercial activated carbon Calgon BPL was also tested and used as reference material for the separation process. Experimental results show that the performance of the different adsorbents, based on the calculated S parameter, may be very different depending on whether data is derived from pure component adsorption isotherms or from breakthrough adsorption experiments. Under dynamic flow conditions, activated carbons produced in this study show a great potential to be applied to a CO2/CH4 separation for biogas upgrading purposes. Further research is envisioned in order to define a PSA process that maximizes the purity and recovery of CH4.Work carried out with financial support from the Spanish MINECO (Project ENE2011-23467), co-financed by the European Regional Development Fund (ERDF). N.A-G. acknowledges a fellowship from the Spanish MINECO (FPI program), co-financed by the European Social Fund.Peer reviewedElsevierConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201520152014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/111587reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1016/j.egypro.2014.11.688Síinfo:eu-repo/semantics/openAccessoai:dnet:digitalcsic_::fdad73af221046a7a60811f6b0e7d68e2026-05-22T06:33:51Z
dc.title.none.fl_str_mv Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
title Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
spellingShingle Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
Álvarez Gutiérrez, Noelia
Biogas upgrading
Biomass
CO2 adsorption
title_short Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
title_full Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
title_fullStr Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
title_full_unstemmed Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
title_sort Towards Bio-upgrading of Biogas: Biomass Waste-based Adsorbents
dc.creator.none.fl_str_mv Álvarez Gutiérrez, Noelia
García López, Susana
Gil Matellanes, María Victoria
Rubiera González, Fernando
Pevida García, Covadonga
author Álvarez Gutiérrez, Noelia
author_facet Álvarez Gutiérrez, Noelia
García López, Susana
Gil Matellanes, María Victoria
Rubiera González, Fernando
Pevida García, Covadonga
author_role author
author2 García López, Susana
Gil Matellanes, María Victoria
Rubiera González, Fernando
Pevida García, Covadonga
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Biogas upgrading
Biomass
CO2 adsorption
topic Biogas upgrading
Biomass
CO2 adsorption
description 12th International Conference on Greenhouse Gas Control Technologies, GHGT-12
publishDate 2014
dc.date.none.fl_str_mv 2014
2015
2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/111587
url http://hdl.handle.net/10261/111587
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://dx.doi.org/10.1016/j.egypro.2014.11.688

dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
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