Large linear magnetoelectric effect and field-induced ferromagnetism and ferroelectricity in DyCrO4

[EN] All the magnetoelectric properties of scheelite-type DyCrO are characterized by temperature- and field-dependent magnetization, specific heat, permittivity, electric polarization, and neutron diffraction measurements. Upon application of a magnetic field within ±3 T, the nonpolar collinear anti...

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Bibliographic Details
Authors: Shen, Xudong, Zhou, Long, Chai, Yisheng, Wu, Yan, Liu, Zhehong, Yin, Yunyu, Cao, Huibo, Dela Cruz, Clarina, Sun, Young, Jin, Changqing, Muñoz, Ángel, Alonso, J. A., Long, Youwen
Format: article
Status:Published version
Publication Date:2019
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/211176
Online Access:http://hdl.handle.net/10261/211176
Access Level:Open access
Keyword:Magnetoelectric properties
DyCrO4
Ferroelectricity
Ferromagnetism
Description
Summary:[EN] All the magnetoelectric properties of scheelite-type DyCrO are characterized by temperature- and field-dependent magnetization, specific heat, permittivity, electric polarization, and neutron diffraction measurements. Upon application of a magnetic field within ±3 T, the nonpolar collinear antiferromagnetic structure leads to a large linear magnetoelectric effect with a considerable coupling coefficient. An applied electric field can induce the converse linear magnetoelectric effect, realizing magnetic field control of ferroelectricity and electric field control of magnetism. Furthermore, a higher magnetic field (>3 T) can cause a metamagnetic transition from the initially collinear antiferromagnetic structure to a canted structure, generating a large ferromagnetic magnetization up to 7.0 μ f.u.. Moreover, the new spin structure can break the space inversion symmetry, yielding ferroelectric polarization, which leads to coupling of ferromagnetism and ferroelectricity with a large ferromagnetic component.