Structural and magnetic behavior of Fe(Nb,Zr) rich alloys produced by mechanical alloying

Fe80Nb7B12Cu1 and Fe80(NiZr)7B12Cu1, nanocrystalline alloys were synthesized in two high-energy ball milling devices (planetary, shaker). The microstructure, thermal and magnetic properties of the milled powders were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC) a...

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Detalles Bibliográficos
Autores: Carrillo Berlanga, Albert, Escoda i Acero, Ma. Lluïsa, Saurina Canals, Joan, Suñol Martínez, Joan Josep
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/18354
Acceso en línea:http://hdl.handle.net/10256/18354
Access Level:acceso abierto
Palabra clave:Materials nanoestructurats -- Aliatges
Nanostructured materials -- Alloys
Substàncies amorfes -- Aliatges
Amorphous substances -- Alloys
Electromagnetisme
Electromagnetism
Termoquímica
Thermochemistry
Calorimetria
Calorimetry
Metalls de transició -- Aliatges
Transition metals -- Alloys
Aliatges amb memòria de forma
Shape memory alloys
Descripción
Sumario:Fe80Nb7B12Cu1 and Fe80(NiZr)7B12Cu1, nanocrystalline alloys were synthesized in two high-energy ball milling devices (planetary, shaker). The microstructure, thermal and magnetic properties of the milled powders were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and vibrating sample magnetometry (VSM); respectively. Milling device influences the microstructure and properties of final products. The results suggest more energetic milling in shaker mill. The main phase is always bcc Fe rich solid solution. Nevertheless, in Fe80Nb7B12Cu1 alloy minor Nb(B) phase is found after shaker milling and in Fe80(NiZr)7B12Cu1 alloy a low crystalline size Zr rich phase after planetary milling. Crystalline grain size ranges between 9.5 and 15.1 nm; lower values correspond to alloys with a second minor phase. Coercivity values ranges between 28.6 and 36.9 Oe