Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion

Photon upconversion (UC) based on triplet-triplet annihilation is a very promising phenomenon with potential application in several areas, though, due to the intrinsic mechanism, the achievement of diffusion-limited solid materials with air-stable UC is still a challenge. Herein, we report UC coordi...

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Autores: Zhang, Junda|||0000-0001-8483-2928, Ruiz-Molina, Daniel|||0000-0002-6844-8421, Novio, Fernando|||0000-0002-1517-3612, Roscini, Claudio|||0000-0002-0157-8934
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:272470
Acceso en línea:https://ddd.uab.cat/record/272470
https://dx.doi.org/urn:doi:10.1021/acsami.2c16354
Access Level:acceso abierto
Palabra clave:Triplet-triplet annihilation
Upconversion
Coordination polymer nanoparticles
Metal-organic framework
Luminescent solar concentrators
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spelling Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable UpconversionZhang, Junda|||0000-0001-8483-2928Ruiz-Molina, Daniel|||0000-0002-6844-8421Novio, Fernando|||0000-0002-1517-3612Roscini, Claudio|||0000-0002-0157-8934Triplet-triplet annihilationUpconversionCoordination polymer nanoparticlesMetal-organic frameworkLuminescent solar concentratorsPhoton upconversion (UC) based on triplet-triplet annihilation is a very promising phenomenon with potential application in several areas, though, due to the intrinsic mechanism, the achievement of diffusion-limited solid materials with air-stable UC is still a challenge. Herein, we report UC coordination polymer nanoparticles (CPNs) combining sensitizer and emitter molecules especially designed with alkyl spacers that promote the amorphous character. Beyond the characteristic constraints of crystalline MOFs, amorphous CPNs facilitate high dye density and flexible ratio tunability. To show the universality of the approach, two types of UC-CPNs are reported, exhibiting highly photostable UC in two different visible spectral regions. Given their nanoscale, narrow size distribution, and good chemical/colloidal stability in water, the CPNs were also successfully printed as anticounterfeiting patterns and used to make highly transparent and photostable films for luminescent solar concentrators, both showing air-stable UC. 22023-01-0120232023-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/272470https://dx.doi.org/urn:doi:10.1021/acsami.2c16354reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-127983OB-C21Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 SEV-2017-0706European Commission https://doi.org/10.13039/501100000780 754558open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2724702026-06-06T12:50:31Z
dc.title.none.fl_str_mv Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
title Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
spellingShingle Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
Zhang, Junda|||0000-0001-8483-2928
Triplet-triplet annihilation
Upconversion
Coordination polymer nanoparticles
Metal-organic framework
Luminescent solar concentrators
title_short Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
title_full Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
title_fullStr Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
title_full_unstemmed Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
title_sort Water-Stable Upconverting Coordination Polymer Nanoparticles for Transparent Films and Anticounterfeiting Patterns with Air-Stable Upconversion
dc.creator.none.fl_str_mv Zhang, Junda|||0000-0001-8483-2928
Ruiz-Molina, Daniel|||0000-0002-6844-8421
Novio, Fernando|||0000-0002-1517-3612
Roscini, Claudio|||0000-0002-0157-8934
author Zhang, Junda|||0000-0001-8483-2928
author_facet Zhang, Junda|||0000-0001-8483-2928
Ruiz-Molina, Daniel|||0000-0002-6844-8421
Novio, Fernando|||0000-0002-1517-3612
Roscini, Claudio|||0000-0002-0157-8934
author_role author
author2 Ruiz-Molina, Daniel|||0000-0002-6844-8421
Novio, Fernando|||0000-0002-1517-3612
Roscini, Claudio|||0000-0002-0157-8934
author2_role author
author
author
dc.subject.none.fl_str_mv Triplet-triplet annihilation
Upconversion
Coordination polymer nanoparticles
Metal-organic framework
Luminescent solar concentrators
topic Triplet-triplet annihilation
Upconversion
Coordination polymer nanoparticles
Metal-organic framework
Luminescent solar concentrators
description Photon upconversion (UC) based on triplet-triplet annihilation is a very promising phenomenon with potential application in several areas, though, due to the intrinsic mechanism, the achievement of diffusion-limited solid materials with air-stable UC is still a challenge. Herein, we report UC coordination polymer nanoparticles (CPNs) combining sensitizer and emitter molecules especially designed with alkyl spacers that promote the amorphous character. Beyond the characteristic constraints of crystalline MOFs, amorphous CPNs facilitate high dye density and flexible ratio tunability. To show the universality of the approach, two types of UC-CPNs are reported, exhibiting highly photostable UC in two different visible spectral regions. Given their nanoscale, narrow size distribution, and good chemical/colloidal stability in water, the CPNs were also successfully printed as anticounterfeiting patterns and used to make highly transparent and photostable films for luminescent solar concentrators, both showing air-stable UC.
publishDate 2023
dc.date.none.fl_str_mv 2
2023-01-01
2023
2023-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/272470
https://dx.doi.org/urn:doi:10.1021/acsami.2c16354
url https://ddd.uab.cat/record/272470
https://dx.doi.org/urn:doi:10.1021/acsami.2c16354
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2021-127983OB-C21
Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 SEV-2017-0706
European Commission https://doi.org/10.13039/501100000780 754558
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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