Hierarchical domain structures in buckled ferroelectric free sheets

Flat elastic sheets tend to display wrinkles and folds. From pieces of clothing down to two-dimensional crystals, these corrugations appear in response to strain generated by sheet compression or stretching, thermal or mechanical mismatch with other elastic layers, or surface tension. Extensively st...

Descripción completa

Detalles Bibliográficos
Autores: Pesquera, David, Cordero-Edwards, Kumara, Checa, Martí, Ivanov, Ilia, Casals, Blai, Rosado, Marcos, Caicedo, José Manuel, Casado-Zueras, Laura, Pablo-Navarro, Javier, Magén, César, Santiso, José, Domingo, Neus, Catalán, Gustau, Sandiumenge, Felip
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/391553
Acceso en línea:http://hdl.handle.net/10261/391553
https://api.elsevier.com/content/abstract/scopus_id/105003992808
Access Level:acceso abierto
Palabra clave:Buckling
Ferroelastic-ferroelectrics
Freestanding oxides
Hierarchical domain structures
id ES_89ff279967ba8e13b89a84c50c2fc7ea
oai_identifier_str oai:digital.csic.es:10261/391553
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Hierarchical domain structures in buckled ferroelectric free sheets
title Hierarchical domain structures in buckled ferroelectric free sheets
spellingShingle Hierarchical domain structures in buckled ferroelectric free sheets
Pesquera, David
Buckling
Ferroelastic-ferroelectrics
Freestanding oxides
Hierarchical domain structures
title_short Hierarchical domain structures in buckled ferroelectric free sheets
title_full Hierarchical domain structures in buckled ferroelectric free sheets
title_fullStr Hierarchical domain structures in buckled ferroelectric free sheets
title_full_unstemmed Hierarchical domain structures in buckled ferroelectric free sheets
title_sort Hierarchical domain structures in buckled ferroelectric free sheets
dc.creator.none.fl_str_mv Pesquera, David
Cordero-Edwards, Kumara
Checa, Martí
Ivanov, Ilia
Casals, Blai
Rosado, Marcos
Caicedo, José Manuel
Casado-Zueras, Laura
Pablo-Navarro, Javier
Magén, César
Santiso, José
Domingo, Neus
Catalán, Gustau
Sandiumenge, Felip
author Pesquera, David
author_facet Pesquera, David
Cordero-Edwards, Kumara
Checa, Martí
Ivanov, Ilia
Casals, Blai
Rosado, Marcos
Caicedo, José Manuel
Casado-Zueras, Laura
Pablo-Navarro, Javier
Magén, César
Santiso, José
Domingo, Neus
Catalán, Gustau
Sandiumenge, Felip
author_role author
author2 Cordero-Edwards, Kumara
Checa, Martí
Ivanov, Ilia
Casals, Blai
Rosado, Marcos
Caicedo, José Manuel
Casado-Zueras, Laura
Pablo-Navarro, Javier
Magén, César
Santiso, José
Domingo, Neus
Catalán, Gustau
Sandiumenge, Felip
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Fundación la Caixa
Ministerio de Industria y Competitividad (España)
Agencia Estatal de Investigación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
European Commission
Ministerio de Universidades (España)
Generalitat de Catalunya
Gobierno de Aragón
Department of Energy (US)
Pesquera, David [0000-0003-0681-3371]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Buckling
Ferroelastic-ferroelectrics
Freestanding oxides
Hierarchical domain structures
topic Buckling
Ferroelastic-ferroelectrics
Freestanding oxides
Hierarchical domain structures
description Flat elastic sheets tend to display wrinkles and folds. From pieces of clothing down to two-dimensional crystals, these corrugations appear in response to strain generated by sheet compression or stretching, thermal or mechanical mismatch with other elastic layers, or surface tension. Extensively studied in metals, polymers and, — more recently — in van der Waals exfoliated layers, with the advent of thin single crystal freestanding films of complex oxides, researchers are now paying attention to novel microstructural effects induced by bending ferroelectric-ferroelastics, where polarization is strongly coupled to lattice deformation. Here we show that wrinkle undulations in BaTiO<inf>3</inf> sheets bonded to a viscoelastic substrate transform into a buckle delamination geometry when transferred onto a rigid substrate. Using spatially resolved techniques at different scales (Raman, scanning probe and electron microscopy), we show how these delaminations in the free BaTiO<inf>3</inf> sheets display a self-organization of ferroelastic domains along the buckle profile that strongly differs from the more studied sinusoidal wrinkle geometry. Moreover, we disclose the hierarchical distribution of a secondary set of domains induced by the misalignment of these folding structures from the preferred in-plane crystallographic orientations. Our results disclose the relevance of the morphology and orientation of buckling instabilities in ferroelectric free sheets, for the stabilization of different domain structures, pointing to new routes for domain engineering of ferroelectrics in flexible oxide sheets.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/391553
https://api.elsevier.com/content/abstract/scopus_id/105003992808
url http://hdl.handle.net/10261/391553
https://api.elsevier.com/content/abstract/scopus_id/105003992808
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-108573GB-C21
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-140589NB-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112914RB-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147211OB-C22
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CCEX2021-001214-S
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2023-001263-S
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2023-001286-S
info:eu-repo/grantAgreement/EC/H2020/823713
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.actamat.2025.121080
https://doi.org/10.1016/j.actamat.2025.121080
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869412668139372544
spelling Hierarchical domain structures in buckled ferroelectric free sheetsPesquera, DavidCordero-Edwards, KumaraCheca, MartíIvanov, IliaCasals, BlaiRosado, MarcosCaicedo, José ManuelCasado-Zueras, LauraPablo-Navarro, JavierMagén, CésarSantiso, JoséDomingo, NeusCatalán, GustauSandiumenge, FelipBucklingFerroelastic-ferroelectricsFreestanding oxidesHierarchical domain structuresFlat elastic sheets tend to display wrinkles and folds. From pieces of clothing down to two-dimensional crystals, these corrugations appear in response to strain generated by sheet compression or stretching, thermal or mechanical mismatch with other elastic layers, or surface tension. Extensively studied in metals, polymers and, — more recently — in van der Waals exfoliated layers, with the advent of thin single crystal freestanding films of complex oxides, researchers are now paying attention to novel microstructural effects induced by bending ferroelectric-ferroelastics, where polarization is strongly coupled to lattice deformation. Here we show that wrinkle undulations in BaTiO<inf>3</inf> sheets bonded to a viscoelastic substrate transform into a buckle delamination geometry when transferred onto a rigid substrate. Using spatially resolved techniques at different scales (Raman, scanning probe and electron microscopy), we show how these delaminations in the free BaTiO<inf>3</inf> sheets display a self-organization of ferroelastic domains along the buckle profile that strongly differs from the more studied sinusoidal wrinkle geometry. Moreover, we disclose the hierarchical distribution of a secondary set of domains induced by the misalignment of these folding structures from the preferred in-plane crystallographic orientations. Our results disclose the relevance of the morphology and orientation of buckling instabilities in ferroelectric free sheets, for the stabilization of different domain structures, pointing to new routes for domain engineering of ferroelectrics in flexible oxide sheets.D.P. acknowledges funding from ‘la Caixa’ Foundation fellowship (ID 100010434). The authors acknowledge the Spanish Ministry of Industry, Economy and Competitiveness (MINECO) through Grants no PID2019–108573GB-C21, PID2022–140589NB-I00, PID2020–112914RB-I00 and PID2023–147211OB-C22 funded by Grant No MCIN/AEI/10.13039/501100011033. The Micro Raman imaging research was conducted as part of a user project at the Center for Nanophase Materials Sciences (CNMS), which is a US Department of Energy, Office of Science User Facility at Oak Ridge National Laboratory. Authors acknowledge the use of instrumentation financed through Grant IU16–014206 (METCAM-FIB) to ICN2 funded by the European Union through the European Regional Development Fund (ERDF), with the support of the Ministry of Research and Universities, and Generalitat de Catalunya. The ICN2 is funded by the CERCA programme/Generalitat de Catalunya and by the Severo Ochoa Centres of Excellence Programme, funded by the Spanish Research Agency (AEI, CEX2021–001214-S). The ICMAB is funded the Severo Ochoa Centres of Excellence Programme, funded by the Spanish Research Agency (AEI, CEX2023–001263-S). The INMA is funded by the Severo Ochoa Centres of Excellence Programme (AEI, CEX2023–001286-S). The authors acknowledge the European’s Union Horizon 2020 research and innovation programme under Grant No 823713-ESTEEM3. This work was also funded from Regional Gobierno de Aragon through Project Nos. E13_23R, including FEDER funding. The authors also acknowledge the use of instrumentation as well as the technical advice provided by the National Facility ELECMI ICTS, node «Laboratorio de Microscopias Avanzadas (LMA)» at «Universidad de Zaragoza». The authors are grateful to Dr. Kapil Gupta for assistance with the Spectra electron microscope at the Joint Electron Microscopy Centre at ALBA synchrotron (JEMCA).With funding from the Spanish government through the "Severo Ochoa Centre of Excelence" accreditation (CEX2021–001214-S).With funding from the Spanish government through the "Severo Ochoa Centre of Excelence" accreditation (CEX2023–001263-S).With funding from the Spanish government through the "Severo Ochoa Centre of Excelence" accreditation (CEX2023–001286-S).Peer reviewedElsevierFundación la CaixaMinisterio de Industria y Competitividad (España)Agencia Estatal de Investigación (España)Ministerio de Ciencia, Innovación y Universidades (España)European CommissionMinisterio de Universidades (España)Generalitat de CatalunyaGobierno de AragónDepartment of Energy (US)Pesquera, David [0000-0003-0681-3371]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/391553https://api.elsevier.com/content/abstract/scopus_id/105003992808reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-108573GB-C21info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-140589NB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112914RB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147211OB-C22info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CCEX2021-001214-Sinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2023-001263-Sinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/CEX2023-001286-Sinfo:eu-repo/grantAgreement/EC/H2020/823713The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.actamat.2025.121080https://doi.org/10.1016/j.actamat.2025.121080Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3915532026-05-22T06:33:51Z
score 15,812429

Similares en LA Referencia