Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs

The interaction of Mn(ClO4)2·6H2O with salicylaldoxime (H2sao) in the presence of nonsteroidal anti-inflammatory drug (NSAID) sodium diclofenac (Nadicl) or indomethacin (Hindo) leads to the formation of the hexanuclear Mn(III) clusters [Mn6(O)2(dicl)2(sao)6(CH3OH)6] (1) and [Mn6(O)2(indo)2(sao)6(H2O...

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Autores: Tarushi, Alketa, Hatzidimitriou, Antonios G., Estrader i Bofarull, Marta, Kessissoglou, Dimitris P., Tangoulis, Vassilis, Psomas, George
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/175936
Acceso en línea:https://hdl.handle.net/2445/175936
Access Level:acceso abierto
Palabra clave:Manganès
Agents antiinflamatoris
Compostos complexos
Manganese
Antiinflammatory agents
Complex compounds
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spelling Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugsTarushi, AlketaHatzidimitriou, Antonios G.Estrader i Bofarull, MartaKessissoglou, Dimitris P.Tangoulis, VassilisPsomas, GeorgeManganèsAgents antiinflamatorisCompostos complexosManganeseAntiinflammatory agentsComplex compoundsThe interaction of Mn(ClO4)2·6H2O with salicylaldoxime (H2sao) in the presence of nonsteroidal anti-inflammatory drug (NSAID) sodium diclofenac (Nadicl) or indomethacin (Hindo) leads to the formation of the hexanuclear Mn(III) clusters [Mn6(O)2(dicl)2(sao)6(CH3OH)6] (1) and [Mn6(O)2(indo)2(sao)6(H2O)4] (2) both characterized as stepladder inverse-9-metallacrown-3 accommodating dicl- or indo- ligands, respectively. When the interaction of MnCl2·4H2O with Nadicl or Hindo is in the absence of H2sao, the mononuclear Mn(II) complexes [Mn(dicl)2(CH3OH)4] (3) and [Mn(indo)2(CH3OH)4] (4) were isolated. The complexes were characterized by physicochemical and spectroscopic techniques, and the structure of complexes 1 and 2 was characterized by X-ray crystallography. Magnetic measurements (dc and ac) were carried out in order to investigate the nature of magnetic interactions between the magnetic ions and the overall magnetic behavior of the complexes.American Chemical Society2017info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://hdl.handle.net/2445/175936Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b00655Inorganic Chemistry, 2017, vol. 56, num. 12, p. 7048-7057https://doi.org/10.1021/acs.inorgchem.7b00655(c) American Chemical Society , 2017info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1759362026-05-27T06:46:51Z
dc.title.none.fl_str_mv Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
title Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
spellingShingle Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
Tarushi, Alketa
Manganès
Agents antiinflamatoris
Compostos complexos
Manganese
Antiinflammatory agents
Complex compounds
title_short Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
title_full Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
title_fullStr Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
title_full_unstemmed Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
title_sort Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
dc.creator.none.fl_str_mv Tarushi, Alketa
Hatzidimitriou, Antonios G.
Estrader i Bofarull, Marta
Kessissoglou, Dimitris P.
Tangoulis, Vassilis
Psomas, George
author Tarushi, Alketa
author_facet Tarushi, Alketa
Hatzidimitriou, Antonios G.
Estrader i Bofarull, Marta
Kessissoglou, Dimitris P.
Tangoulis, Vassilis
Psomas, George
author_role author
author2 Hatzidimitriou, Antonios G.
Estrader i Bofarull, Marta
Kessissoglou, Dimitris P.
Tangoulis, Vassilis
Psomas, George
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Manganès
Agents antiinflamatoris
Compostos complexos
Manganese
Antiinflammatory agents
Complex compounds
topic Manganès
Agents antiinflamatoris
Compostos complexos
Manganese
Antiinflammatory agents
Complex compounds
description The interaction of Mn(ClO4)2·6H2O with salicylaldoxime (H2sao) in the presence of nonsteroidal anti-inflammatory drug (NSAID) sodium diclofenac (Nadicl) or indomethacin (Hindo) leads to the formation of the hexanuclear Mn(III) clusters [Mn6(O)2(dicl)2(sao)6(CH3OH)6] (1) and [Mn6(O)2(indo)2(sao)6(H2O)4] (2) both characterized as stepladder inverse-9-metallacrown-3 accommodating dicl- or indo- ligands, respectively. When the interaction of MnCl2·4H2O with Nadicl or Hindo is in the absence of H2sao, the mononuclear Mn(II) complexes [Mn(dicl)2(CH3OH)4] (3) and [Mn(indo)2(CH3OH)4] (4) were isolated. The complexes were characterized by physicochemical and spectroscopic techniques, and the structure of complexes 1 and 2 was characterized by X-ray crystallography. Magnetic measurements (dc and ac) were carried out in order to investigate the nature of magnetic interactions between the magnetic ions and the overall magnetic behavior of the complexes.
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/175936
url https://hdl.handle.net/2445/175936
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b00655
Inorganic Chemistry, 2017, vol. 56, num. 12, p. 7048-7057
https://doi.org/10.1021/acs.inorgchem.7b00655
dc.rights.none.fl_str_mv (c) American Chemical Society , 2017
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) American Chemical Society , 2017
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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