Correlation between ion hopping conductivity and near constant loss in ionic conductors

For ionic conductivity relaxation in ionically conducting materials we predict in the framework of the coupling model that the magnitude of the ubiquitous near constant loss correlates with the activation energy E_(a) for independent ion hopping. Using experimental data of a variety of ionic conduct...

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Detalles Bibliográficos
Autores: León Yebra, Carlos, Ngai, K. L., Rivera Calzada, Alberto Carlos
Tipo de recurso: artículo
Fecha de publicación:2004
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/51435
Acceso en línea:https://hdl.handle.net/20.500.14352/51435
Access Level:acceso abierto
Palabra clave:537
AC conductivity
Oxide glasses
Relaxation
Behavior
Universality
Frequency
Crystals
Spectra: Solids
Melts.
Electricidad
Electrónica (Física)
2202.03 Electricidad
Descripción
Sumario:For ionic conductivity relaxation in ionically conducting materials we predict in the framework of the coupling model that the magnitude of the ubiquitous near constant loss correlates with the activation energy E_(a) for independent ion hopping. Using experimental data of a variety of ionic conductors, this correlation has been borne out. The model also explains the observed correlation between the magnitude of the near constant loss and the value of the dc conductivity at room temperature, as well as the temperature dependence for the near constant loss.