A straightforward synthesis of 5′-peptide oligonucleotide conjugates using Nα-Fmoc-protected amino acids

(Chemical Equation Presented) 5′-Peptide oligonucleotide conjugates were prepared stepwise on a single support using Nα-Fmoc- protected amino acids and unprotected phosphate groups. The method uses commercially available reagents and is successful with most natural amino acids. The simplicity of the...

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Detalhes bibliográficos
Autores: Ocampo, Sandra M., Albericio, Fernando, Fernández, Irene F., Vilaseca, Marta, Eritja Casadellà, Ramón
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2005
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/124874
Acesso em linha:http://hdl.handle.net/10261/124874
Access Level:acceso abierto
Palavra-chave:fluorene derivative
Amino acid
oligonucleotides
Fluorene
chemical structure
Descrição
Resumo:(Chemical Equation Presented) 5′-Peptide oligonucleotide conjugates were prepared stepwise on a single support using Nα-Fmoc- protected amino acids and unprotected phosphate groups. The method uses commercially available reagents and is successful with most natural amino acids. The simplicity of the method may encourage researchers to prepare new oligonucleotide-peptide conjugates with novel properties.