New epoxy thermosets derived from clove oil prepared by epoxy-amine curing
New thermosets from a triglycidyl eugenol derivative (3EPOEU) as a renewable epoxy monomer were obtained by an epoxy-amine curing process. A commercially-available Jeffamine® and isophorone diamine, both obtained from renewable resources, were used as crosslinking agents, and the materials obtained...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/183314 |
| Acceso en línea: | https://hdl.handle.net/2117/183314 https://dx.doi.org/10.3390/polym12010044 |
| Access Level: | acceso abierto |
| Palabra clave: | Heat resistant plastics Calorimetry Polymers Chemical reactions Thermosets Eugenol Renewable resources Plàstics termostables Calorimetria Polímers Reaccions químiques Àrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers Àrees temàtiques de la UPC::Enginyeria química Àrees temàtiques de la UPC::Enginyeria química::Química orgànica Àrees temàtiques de la UPC::Enginyeria química::Química orgànica::Compostos orgànics |
| Sumario: | New thermosets from a triglycidyl eugenol derivative (3EPOEU) as a renewable epoxy monomer were obtained by an epoxy-amine curing process. A commercially-available Jeffamine® and isophorone diamine, both obtained from renewable resources, were used as crosslinking agents, and the materials obtained were compared with those obtained from a standard diglycidylether of bisphenol A (DGEBA). The evolution of the curing process was studied by differential scanning calorimetry and the materials obtained were characterized by means of calorimetry, thermogravimetry, thermodynamomechanical analysis, stress–strain tests and microindentation. 3EPOEU formulations were slightly less reactive, and the thermosets obtained showed higher Tgs than those prepared from DGEBA, since they had higher crosslinking density than formulations with DGEBA because of the more compact structure and higher functionality of the eugenol derivative. 3EPOEU thermosets showed good thermal stability and mechanical properties. The results obtained in this study allow us to conclude that the triglycidyl derivative of eugenol, 3EPOEU, is a safe and environmentally friendly alternative to DGEBA. |
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