A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block

The synthesis and X-ray structure of a new and readily available exTTF derivative (6) bearing a methyltriphenylphosphonium bromide moiety as a new building block for the construction of electroactive molecules is reported. The phosphonium salt 6, which was prepared in one step from 2-hydroxymethyl-e...

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Detalhes bibliográficos
Autores: Molina Ontoria, Agustín, García Cervilla, Raúl, Gouloumis, Andreas, Giacalone, Francesco, Torres, M. Rosario, Martín León, Nazario
Tipo de documento: artigo
Data de publicação:2012
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositório:Docta Complutense
Idioma:inglês
OAI Identifier:oai:docta.ucm.es:20.500.14352/115076
Acesso em linha:https://hdl.handle.net/20.500.14352/115076
Access Level:Acceso aberto
Palavra-chave:547
Materials
Fused-ring systems
Conjugation
Donor-acceptor systems
Pi interactions
Olefination
Química orgánica (Química)
2306 Química Orgánica
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oai_identifier_str oai:docta.ucm.es:20.500.14352/115076
network_acronym_str ES
network_name_str España
repository_id_str
spelling A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building blockMolina Ontoria, AgustínGarcía Cervilla, RaúlGouloumis, AndreasGiacalone, FrancescoTorres, M. RosarioMartín León, Nazario547MaterialsFused-ring systemsConjugationDonor-acceptor systemsPi interactionsOlefinationQuímica orgánica (Química)2306 Química OrgánicaThe synthesis and X-ray structure of a new and readily available exTTF derivative (6) bearing a methyltriphenylphosphonium bromide moiety as a new building block for the construction of electroactive molecules is reported. The phosphonium salt 6, which was prepared in one step from 2-hydroxymethyl-exTTF as a stable yellow solid in 84 % yield, efficiently undergoes Wittig olefination reactions with a variety of aldehydes to predominantly form the E isomer. Electronic spectra and cyclic voltammetry of the novel compounds reveal the electronic communication between the electroactive units.WILEY-VCHUniversidad Complutense de Madrid20122012-05-2220122012-05-22journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/115076reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/1150762026-06-02T12:44:21Z
dc.title.none.fl_str_mv A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
title A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
spellingShingle A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
Molina Ontoria, Agustín
547
Materials
Fused-ring systems
Conjugation
Donor-acceptor systems
Pi interactions
Olefination
Química orgánica (Química)
2306 Química Orgánica
title_short A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
title_full A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
title_fullStr A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
title_full_unstemmed A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
title_sort A straightforward electroactive π‐extended tetrathiafulvalene (exTTF) building block
dc.creator.none.fl_str_mv Molina Ontoria, Agustín
García Cervilla, Raúl
Gouloumis, Andreas
Giacalone, Francesco
Torres, M. Rosario
Martín León, Nazario
author Molina Ontoria, Agustín
author_facet Molina Ontoria, Agustín
García Cervilla, Raúl
Gouloumis, Andreas
Giacalone, Francesco
Torres, M. Rosario
Martín León, Nazario
author_role author
author2 García Cervilla, Raúl
Gouloumis, Andreas
Giacalone, Francesco
Torres, M. Rosario
Martín León, Nazario
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 547
Materials
Fused-ring systems
Conjugation
Donor-acceptor systems
Pi interactions
Olefination
Química orgánica (Química)
2306 Química Orgánica
topic 547
Materials
Fused-ring systems
Conjugation
Donor-acceptor systems
Pi interactions
Olefination
Química orgánica (Química)
2306 Química Orgánica
description The synthesis and X-ray structure of a new and readily available exTTF derivative (6) bearing a methyltriphenylphosphonium bromide moiety as a new building block for the construction of electroactive molecules is reported. The phosphonium salt 6, which was prepared in one step from 2-hydroxymethyl-exTTF as a stable yellow solid in 84 % yield, efficiently undergoes Wittig olefination reactions with a variety of aldehydes to predominantly form the E isomer. Electronic spectra and cyclic voltammetry of the novel compounds reveal the electronic communication between the electroactive units.
publishDate 2012
dc.date.none.fl_str_mv 2012
2012-05-22
2012
2012-05-22
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/115076
url https://hdl.handle.net/20.500.14352/115076
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv WILEY-VCH
publisher.none.fl_str_mv WILEY-VCH
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869412488993308672
score 15.811543

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