An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites
Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme)
| Autores: | , , , , |
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| Tipo de documento: | artigo |
| Estado: | Versão publicada |
| Data de publicação: | 2013 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositório: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/12260 |
| Acesso em linha: | http://hdl.handle.net/10256/12260 |
| Access Level: | Acesso embargado |
| Palavra-chave: | Catàlisi Catalysis Catàlisi homogènia Homogeneous catalysis Aigua oxigenada Hydrogen peroxide Ferro Iron Catalitzadors de ferro Iron catalysts |
| Resumo: | Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme) |
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