Microwave-Assisted Synthesis of Iron-Based Aerogels with Tailored Textural and Morphological Properties
Iron aerogels have been synthesized by microwave heating for the first time. Therefore, it is essential to optimize this synthesis process to evaluate the possibility of obtaining nanometric materials with tailored properties and fitting them to the needs of different applications. Herein, the effec...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/340597 |
| Acceso en línea: | http://hdl.handle.net/10261/340597 https://api.elsevier.com/content/abstract/scopus_id/85174953875 |
| Access Level: | acceso abierto |
| Palabra clave: | sol-gel reaction designed properties iron oxide metallic nanostructured aerogels microwave heating http://metadata.un.org/sdg/7 http://metadata.un.org/sdg/9 Ensure access to affordable, reliable, sustainable and modern energy for all Build resilient infrastructure, promote inclusive and sustainable industrialization and foster innovation |
| Sumario: | Iron aerogels have been synthesized by microwave heating for the first time. Therefore, it is essential to optimize this synthesis process to evaluate the possibility of obtaining nanometric materials with tailored properties and fitting them to the needs of different applications. Herein, the effect of the ratio between reagents and the time of synthesis on the final textural, morphological, and structural properties has been evaluated. The micro-meso-macroporosity of the samples can be tailored by modifying the ratio between reagents, whereas the time of synthesis has only a slight effect on the microporosity. Both the proportion between reagents and the time of synthesis are essential to controlling the nanometric morphology, making it possible to obtain either cluster- or flake-type structures. Regarding the chemical and structural composition, the samples are mainly composed of iron(II) and iron(III) oxides. However, the percentage of iron(II) can be modulated by changing the ratio between reagents, which implies that it is possible to obtain materials from highly magnetic materials to materials without magnetic properties. This control over the properties of iron aerogels opens a new line of opportunities for the use of this type of material in several fields of applications such as electrochemistry, electrocatalysis, and electrical and electronic engineering. |
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