Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems

A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies a...

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Autores: Pilichos, Evangelos, Tubau Ribot, Ànnia, Speed Castro, Saskia, Font Bardia, Ma. Mercedes, Escuer Fité, Albert, Grabulosa, Arnald, Mayans Ayats, Júlia
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Recursos:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/217061
Acesso em linha:https://hdl.handle.net/2445/217061
Access Level:acceso abierto
Palavra-chave:Radiocristal·lografia
Propietats magnètiques
Òptica
X-ray crystallography
Magnetic properties
Optics
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spelling Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systemsPilichos, EvangelosTubau Ribot, ÀnniaSpeed Castro, SaskiaFont Bardia, Ma. MercedesEscuer Fité, AlbertGrabulosa, ArnaldMayans Ayats, JúliaRadiocristal·lografiaPropietats magnètiquesÒpticaX-ray crystallographyMagnetic propertiesOpticsA new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies appear: the two-dimensional structure [LnIII(dppeO2)1.5(NO3)3(H2O)0.5]n (Ln = Ce (1), Sm (2) and Dy (6)) and the one-dimensional structure [Ln(dppeO2)(NO3)3DMF]n (Ln = Eu (3), Gd (4) and Tb (5)). Some of the Ln-derived complexes have been used as structural probes, while others have been synthesized to use the specific characteristics of each cation to take advantage of their magnetic/luminescence properties. Complex 6 presents slow relaxation of the magnetization while 2, 3 and 5 present emitting properties in the visible range.Royal Society of Chemistry2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://hdl.handle.net/2445/217061Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésReproducció del document publicat a: https://doi.org/10.1039/d2dt03621eDalton Transactions, 2023, vol. 52, num.8, p. 2485-2494https://doi.org/10.1039/d2dt03621ecc-by (c) Pilichos, Evangelos et al., 2023http://creativecommons.org/licenses/by/3.0/es/info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/2170612026-05-27T06:46:51Z
dc.title.none.fl_str_mv Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
title Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
spellingShingle Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
Pilichos, Evangelos
Radiocristal·lografia
Propietats magnètiques
Òptica
X-ray crystallography
Magnetic properties
Optics
title_short Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
title_full Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
title_fullStr Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
title_full_unstemmed Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
title_sort Magnetic and optical studies of a new family of multidimensional and multiproperty PO-lanthanide(iii) derived systems
dc.creator.none.fl_str_mv Pilichos, Evangelos
Tubau Ribot, Ànnia
Speed Castro, Saskia
Font Bardia, Ma. Mercedes
Escuer Fité, Albert
Grabulosa, Arnald
Mayans Ayats, Júlia
author Pilichos, Evangelos
author_facet Pilichos, Evangelos
Tubau Ribot, Ànnia
Speed Castro, Saskia
Font Bardia, Ma. Mercedes
Escuer Fité, Albert
Grabulosa, Arnald
Mayans Ayats, Júlia
author_role author
author2 Tubau Ribot, Ànnia
Speed Castro, Saskia
Font Bardia, Ma. Mercedes
Escuer Fité, Albert
Grabulosa, Arnald
Mayans Ayats, Júlia
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Radiocristal·lografia
Propietats magnètiques
Òptica
X-ray crystallography
Magnetic properties
Optics
topic Radiocristal·lografia
Propietats magnètiques
Òptica
X-ray crystallography
Magnetic properties
Optics
description A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies appear: the two-dimensional structure [LnIII(dppeO2)1.5(NO3)3(H2O)0.5]n (Ln = Ce (1), Sm (2) and Dy (6)) and the one-dimensional structure [Ln(dppeO2)(NO3)3DMF]n (Ln = Eu (3), Gd (4) and Tb (5)). Some of the Ln-derived complexes have been used as structural probes, while others have been synthesized to use the specific characteristics of each cation to take advantage of their magnetic/luminescence properties. Complex 6 presents slow relaxation of the magnetization while 2, 3 and 5 present emitting properties in the visible range.
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/217061
url https://hdl.handle.net/2445/217061
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1039/d2dt03621e
Dalton Transactions, 2023, vol. 52, num.8, p. 2485-2494
https://doi.org/10.1039/d2dt03621e
dc.rights.none.fl_str_mv cc-by (c) Pilichos, Evangelos et al., 2023
http://creativecommons.org/licenses/by/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by (c) Pilichos, Evangelos et al., 2023
http://creativecommons.org/licenses/by/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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