Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
A hydrogenated frustrated Lewis pair ([TMPH][HB(CF) ]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the f...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:215270 |
| Acceso en línea: | https://ddd.uab.cat/record/215270 https://dx.doi.org/urn:doi:10.1039/c8sc04729d |
| Access Level: | acceso abierto |
| Palabra clave: | Controlled growth Cyanoacrylates Frustrated lewis pairs Ionic polymerization Living anionic polymerization Monomer addition |
| Sumario: | A hydrogenated frustrated Lewis pair ([TMPH][HB(CF) ]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials. |
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