“Thermal Analysis Study of Diol-Based Precursors for Chemical Solution Deposition of 0.7 Pb(Mg1/3Nb2/3)O3-0.3 PbTiO3 Thin Films”

Thermal decompositions of the precursors for chemical solution deposition of 0.7 Pb(Mg1/3Nb2/3)O3-0.3 PbTiO3 thin films were studied. The precursors were prepared from lead acetate or acetylacetone-modified lead acetate by diol-based route, and dried at 100ºC.Thermal decompositions of the PT, PMN an...

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Detalles Bibliográficos
Autores: Malic, Bárbara, Calzada, M. L., Cilensek, J, Pardo, Lorena, Kosec, Marija
Tipo de recurso: artículo
Fecha de publicación:2011
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/40713
Acceso en línea:http://hdl.handle.net/10261/40713
Access Level:acceso abierto
Palabra clave:Lead
Magnesium
Niobate
Titanate
PMNPT
Sol-gel
Film
Película
Thermal
Analysis
Análisis
Térmico
Descripción
Sumario:Thermal decompositions of the precursors for chemical solution deposition of 0.7 Pb(Mg1/3Nb2/3)O3-0.3 PbTiO3 thin films were studied. The precursors were prepared from lead acetate or acetylacetone-modified lead acetate by diol-based route, and dried at 100ºC.Thermal decompositions of the PT, PMN and PMN-PT precursors in air occur stepwise. Between room temperature and approximately 200ºC the weight loss of a few % is due to evaporation of residual solvents. Organic groups decompose in the 200 - 400ºC and 400-650ºC ranges. The thermal decompositions are affected by the choice of the Pb-compound and chemical composition of the sample.