Effect of Applying Organic Amendments on the Pyrolytic Behavior of a Poplar Energy Crop

Thermal conversion of biomass derived from energy crops is one alternative for the production of energy. In this work, thermogravimetric analysis of poplar biomass was carried out and both the kinetic parameters (activation energy and frequency factor) and characteristic indexes were determined. Fou...

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Detalles Bibliográficos
Autores: Paniagua, Sergio, Gomes, Ricardo Nuno de Coimbra Sampaio, Escapa Santos, Carla, Otero Cabero, Marta, Calvo Prieto, Luis Fernando
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Universidad de León
Repositorio:BULERIA. Repositorio Institucional de la Universidad de León
OAI Identifier:oai:buleria.unileon.es:10612/17606
Acceso en línea:https://hdl.handle.net/10612/17606
Access Level:acceso abierto
Palabra clave:Ingeniería química
Química
bioenergy
biomass
kinetics
pyrolysis
thermal conversion
Descripción
Sumario:Thermal conversion of biomass derived from energy crops is one alternative for the production of energy. In this work, thermogravimetric analysis of poplar biomass was carried out and both the kinetic parameters (activation energy and frequency factor) and characteristic indexes were determined. Four poplar clones (UNAL, I-214, AF-2 and AF-8) under no fertilization (CONTROL) or under fertilization with either dehydrated composted sewage sludge (BIOSOLIDS) or sludge from dairy wastewater treatment (MUD) were used in this work. Five weight loss stages were identified in the DTG pyrolysis curves: moisture loss, active pyrolysis (two phases), passive pyrolysis and a high-rank pyrolysis phase. Among them, the second pyrolysis active phase was the most representative one. For this stage, BIOSOLIDS-UNAL poplars biomass was the one that achieved the highest weight loss values. The characteristic parameters and indexes (especially P and Pi indexes) also pointed to UNAL poplars under BIOSOLIDS fertilization as the most favourable for pyrolytic thermal conversion.