The molecular structure of Me3TiCp* in the gas phase
The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to ti...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1990 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4633 |
| Acceso en línea: | http://hdl.handle.net/10017/4633 https://dx.doi.org/10.1016/0022-328X(90)80155-S |
| Access Level: | acceso abierto |
| Palabra clave: | Gas phase electron diffraction GED Methyl groups Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | The thermal average molecular structure of Me3TiCp★ has been determined by gas phase electron diffraction (GED). The GED data are consistent with a molecular model in which the TiMe3 fragment has C3v symmetry and the TiCp★ fragment has C5v symmetry. No static tilt of the methyl groups attached to titanium can be detected, although a flattening of the methyl groups with Ti-C-H 103.8(1.2)° is obtained. The Ti-C(Me) bond distance is 210.7(5) pm, and the Ti-C(Cp★) distance 238.0(5) pm. |
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