Lignin-based catalysts for C–C bond-forming reactions

Carbon–carbon (C–C) bond formation is the key reaction in organic synthesis to construct the carbon framework of organic molecules. The continuous shift of science and technology toward eco-friendly and sustainable resources and processes has stimulated the development of catalytic processes for C–C...

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Autores: Díaz Díaz, David, García Martín, Cristina del Mar, Hernández García, José Ignacio, Bonardd, Sebastián
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Universidad de La Laguna (ULL)
Repositorio:RIULL. Repositorio Institucional de la Universidad de La Laguna
OAI Identifier:oai:riull.ull.es:915/42219
Acceso en línea:http://riull.ull.es/xmlui/handle/915/42219
Access Level:acceso abierto
Palabra clave:lignin
catalysis
organic synthesis
C–C bond formation
metal nanoparticles
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spelling Lignin-based catalysts for C–C bond-forming reactionsDíaz Díaz, DavidGarcía Martín, Cristina del MarHernández García, José IgnacioBonardd, Sebastiánlignincatalysisorganic synthesisC–C bond formationmetal nanoparticlesCarbon–carbon (C–C) bond formation is the key reaction in organic synthesis to construct the carbon framework of organic molecules. The continuous shift of science and technology toward eco-friendly and sustainable resources and processes has stimulated the development of catalytic processes for C–C bond formation based on the use of renewable resources. In this context, and among other biopolymer-based materials, lignin has attracted scientific attention in the field of catalysis during the last decade, either through its acid form or as a support for metal ions and metal nanoparticles that drive the catalytic activity. Its heterogeneous nature, as well as its facile preparation and low cost, provide competitive advantages over other homogeneous catalysts. In this review, we have summarized a variety of C–C formation reactions, such as condensations, Michael additions of indoles, and Pd-mediated cross-coupling reactions that were successfully carried out in the presence of lignin-based catalysts. These examples also involve the successful recovery and reuse of the catalyst after the reaction.MDPI202520252023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://riull.ull.es/xmlui/handle/915/42219reponame:RIULL. Repositorio Institucional de la Universidad de La Lagunainstname:Universidad de La Laguna (ULL)InglésMolecules;28 (3513), 2023Atribución 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riull.ull.es:915/422192026-06-22T13:13:57Z
dc.title.none.fl_str_mv Lignin-based catalysts for C–C bond-forming reactions
title Lignin-based catalysts for C–C bond-forming reactions
spellingShingle Lignin-based catalysts for C–C bond-forming reactions
Díaz Díaz, David
lignin
catalysis
organic synthesis
C–C bond formation
metal nanoparticles
title_short Lignin-based catalysts for C–C bond-forming reactions
title_full Lignin-based catalysts for C–C bond-forming reactions
title_fullStr Lignin-based catalysts for C–C bond-forming reactions
title_full_unstemmed Lignin-based catalysts for C–C bond-forming reactions
title_sort Lignin-based catalysts for C–C bond-forming reactions
dc.creator.none.fl_str_mv Díaz Díaz, David
García Martín, Cristina del Mar
Hernández García, José Ignacio
Bonardd, Sebastián
author Díaz Díaz, David
author_facet Díaz Díaz, David
García Martín, Cristina del Mar
Hernández García, José Ignacio
Bonardd, Sebastián
author_role author
author2 García Martín, Cristina del Mar
Hernández García, José Ignacio
Bonardd, Sebastián
author2_role author
author
author
dc.subject.none.fl_str_mv lignin
catalysis
organic synthesis
C–C bond formation
metal nanoparticles
topic lignin
catalysis
organic synthesis
C–C bond formation
metal nanoparticles
description Carbon–carbon (C–C) bond formation is the key reaction in organic synthesis to construct the carbon framework of organic molecules. The continuous shift of science and technology toward eco-friendly and sustainable resources and processes has stimulated the development of catalytic processes for C–C bond formation based on the use of renewable resources. In this context, and among other biopolymer-based materials, lignin has attracted scientific attention in the field of catalysis during the last decade, either through its acid form or as a support for metal ions and metal nanoparticles that drive the catalytic activity. Its heterogeneous nature, as well as its facile preparation and low cost, provide competitive advantages over other homogeneous catalysts. In this review, we have summarized a variety of C–C formation reactions, such as condensations, Michael additions of indoles, and Pd-mediated cross-coupling reactions that were successfully carried out in the presence of lignin-based catalysts. These examples also involve the successful recovery and reuse of the catalyst after the reaction.
publishDate 2023
dc.date.none.fl_str_mv 2023
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://riull.ull.es/xmlui/handle/915/42219
url http://riull.ull.es/xmlui/handle/915/42219
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Molecules;28 (3513), 2023
dc.rights.none.fl_str_mv Atribución 4.0 Internacional
http://creativecommons.org/licenses/by/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución 4.0 Internacional
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv MDPI
publisher.none.fl_str_mv MDPI
dc.source.none.fl_str_mv reponame:RIULL. Repositorio Institucional de la Universidad de La Laguna
instname:Universidad de La Laguna (ULL)
instname_str Universidad de La Laguna (ULL)
reponame_str RIULL. Repositorio Institucional de la Universidad de La Laguna
collection RIULL. Repositorio Institucional de la Universidad de La Laguna
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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