Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses

The transport and reaction processes of linear alkylbenzene sulfonate (LAS) were characterised in columns of agricultural soil with a constant inflow of irrigation water. A pulse input of commercial LAS was performed with different mixtures of soil and sea sand (0/100%, 25/75% and 50/50%) and a cont...

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Detalles Bibliográficos
Autores: Boluda-Botella, N., León, Víctor Manuel, Cases, V., Gomis, V., Prats, D.
Tipo de recurso: artículo
Fecha de publicación:2010
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/321019
Acceso en línea:http://hdl.handle.net/10261/321019
Access Level:acceso abierto
Palabra clave:Medio Marino
Centro Oceanográfico de Murcia
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repository_id_str
spelling Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulsesBoluda-Botella, N.León, Víctor ManuelCases, V.Gomis, V.Prats, D.Medio MarinoCentro Oceanográfico de MurciaThe transport and reaction processes of linear alkylbenzene sulfonate (LAS) were characterised in columns of agricultural soil with a constant inflow of irrigation water. A pulse input of commercial LAS was performed with different mixtures of soil and sea sand (0/100%, 25/75% and 50/50%) and a continuous water flow of approximately 0.5 mL/min. LAS homologue retention was favoured at a higher soil rate, due mainly to higher clay and organic matter contents. C10LAS and C11LAS were less retained in soil columns, and were eluted faster and in higher proportion through soil columns than other homologues. C12LAS and C13LAS showed stronger interactions with soil due to their higher sorption capacity, and a lower proportion was eluted than the lightest homologues. In general, sorption of LAS was reversible and significant fractions were desorbed when the LAS input ceased and they were transported to deeper layers in the soil column, especially for short-chain homologues. Longer LAS homologues were eluted from soil columns, but required an elution of >10 pore-volumes. When there was biodegradation in the soil column, >25% of LAS could be removed, reducing percolation to deeper layers.Sí202320232010info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://hdl.handle.net/10261/321019reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésCentro Oceanográfico de Murciainfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3210192026-05-22T06:33:51Z
dc.title.none.fl_str_mv Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
title Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
spellingShingle Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
Boluda-Botella, N.
Medio Marino
Centro Oceanográfico de Murcia
title_short Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
title_full Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
title_fullStr Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
title_full_unstemmed Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
title_sort Fate of linear alkylbenzene sulfonate in agricultural soil columns during inflow of surfactant pulses
dc.creator.none.fl_str_mv Boluda-Botella, N.
León, Víctor Manuel
Cases, V.
Gomis, V.
Prats, D.
author Boluda-Botella, N.
author_facet Boluda-Botella, N.
León, Víctor Manuel
Cases, V.
Gomis, V.
Prats, D.
author_role author
author2 León, Víctor Manuel
Cases, V.
Gomis, V.
Prats, D.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Medio Marino
Centro Oceanográfico de Murcia
topic Medio Marino
Centro Oceanográfico de Murcia
description The transport and reaction processes of linear alkylbenzene sulfonate (LAS) were characterised in columns of agricultural soil with a constant inflow of irrigation water. A pulse input of commercial LAS was performed with different mixtures of soil and sea sand (0/100%, 25/75% and 50/50%) and a continuous water flow of approximately 0.5 mL/min. LAS homologue retention was favoured at a higher soil rate, due mainly to higher clay and organic matter contents. C10LAS and C11LAS were less retained in soil columns, and were eluted faster and in higher proportion through soil columns than other homologues. C12LAS and C13LAS showed stronger interactions with soil due to their higher sorption capacity, and a lower proportion was eluted than the lightest homologues. In general, sorption of LAS was reversible and significant fractions were desorbed when the LAS input ceased and they were transported to deeper layers in the soil column, especially for short-chain homologues. Longer LAS homologues were eluted from soil columns, but required an elution of >10 pore-volumes. When there was biodegradation in the soil column, >25% of LAS could be removed, reducing percolation to deeper layers.
publishDate 2010
dc.date.none.fl_str_mv 2010
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/321019
url http://hdl.handle.net/10261/321019
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Centro Oceanográfico de Murcia
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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